Journal of the American Chemical Society, volume 137, issue 4, pages 1697-1704
Energetic Salts with π-Stacking and Hydrogen-Bonding Interactions Lead the Way to Future Energetic Materials
1
Department
of Chemistry, University of Idaho, Moscow, Idaho 83844-2343, United States
|
2
Institute
of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900, China
|
3
Indian
Head Explosive Ordnance Disposal Technology Division, The Naval Surface Warfare Center, Indian Head, Maryland 20640, United States
|
4
Naval Research Laboratory, 4555 Overlook Avenue, Washington, D.C. 20375, United States
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Publication type: Journal Article
Publication date: 2015-01-23
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Among energetic materials, there are two significant challenges facing researchers: 1) to develop ionic CHNO explosives with higher densities than their parent nonionic molecules and (2) to achieve a fine balance between high detonation performance and low sensitivity. We report a surprising energetic salt, hydroxylammonium 3-dinitromethanide-1,2,4-triazolone, that exhibits exceptional properties, viz., higher density, superior detonation performance, and improved thermal, impact, and friction stabilities, then those of its precursor, 3-dinitromethyl-1,2,4-triazolone. The solid-state structure features of the new energetic salt were investigated with X-ray diffraction which showed π-stacking and hydrogen-bonding interactions that contribute to closer packing and higher density. According to the experimental results and theoretical analysis, the newly designed energetic salt also gives rise to a workable compromise in high detonation properties and desirable stabilities. These findings will enhance the future prospects for rational energetic materials design and commence a new chapter in this field.
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Zhang J. et al. Energetic Salts with π-Stacking and Hydrogen-Bonding Interactions Lead the Way to Future Energetic Materials // Journal of the American Chemical Society. 2015. Vol. 137. No. 4. pp. 1697-1704.
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Zhang J., Zhang Q., Vo T. T., Parrish D. A., Shreeve J. M. Energetic Salts with π-Stacking and Hydrogen-Bonding Interactions Lead the Way to Future Energetic Materials // Journal of the American Chemical Society. 2015. Vol. 137. No. 4. pp. 1697-1704.
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TY - JOUR
DO - 10.1021/ja5126275
UR - https://doi.org/10.1021/ja5126275
TI - Energetic Salts with π-Stacking and Hydrogen-Bonding Interactions Lead the Way to Future Energetic Materials
T2 - Journal of the American Chemical Society
AU - Vo, Thao T
AU - Parrish, Damon A.
AU - Zhang, Jiaheng
AU - Zhang, Qinghua
AU - Shreeve, Jean'ne M.
PY - 2015
DA - 2015/01/23 00:00:00
PB - American Chemical Society (ACS)
SP - 1697-1704
IS - 4
VL - 137
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2015_Zhang,
author = {Thao T Vo and Damon A. Parrish and Jiaheng Zhang and Qinghua Zhang and Jean'ne M. Shreeve},
title = {Energetic Salts with π-Stacking and Hydrogen-Bonding Interactions Lead the Way to Future Energetic Materials},
journal = {Journal of the American Chemical Society},
year = {2015},
volume = {137},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ja5126275},
number = {4},
pages = {1697--1704},
doi = {10.1021/ja5126275}
}
Cite this
MLA
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Zhang, Jiaheng, et al. “Energetic Salts with π-Stacking and Hydrogen-Bonding Interactions Lead the Way to Future Energetic Materials.” Journal of the American Chemical Society, vol. 137, no. 4, Jan. 2015, pp. 1697-1704. https://doi.org/10.1021/ja5126275.