Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides
Publication type: Journal Article
Publication date: 2009-03-02
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
19253939
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A new rhodium-catalyzed carbozincation of ynamides has been developed, using diorganozinc reagents or functionalized alkylzinc halides. The reactions are highly regio- and stereoselective, allowing access to a wide range of multisubstituted enamides, which are increasingly important building blocks for organic synthesis. Utilization of the alkenylzinc intermediates in further carbon−carbon bond-forming reactions to form trisubstituted enamides is also possible.
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146
Total citations:
146
Citations from 2024:
16
(10%)
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MLA
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GOST
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Gourdet B., Lam H. W. Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides // Journal of the American Chemical Society. 2009. Vol. 131. No. 11. pp. 3802-3803.
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Gourdet B., Lam H. W. Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides // Journal of the American Chemical Society. 2009. Vol. 131. No. 11. pp. 3802-3803.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja900946h
UR - https://doi.org/10.1021/ja900946h
TI - Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides
T2 - Journal of the American Chemical Society
AU - Gourdet, Benoit
AU - Lam, Hon Wai
PY - 2009
DA - 2009/03/02
PB - American Chemical Society (ACS)
SP - 3802-3803
IS - 11
VL - 131
PMID - 19253939
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Gourdet,
author = {Benoit Gourdet and Hon Wai Lam},
title = {Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides},
journal = {Journal of the American Chemical Society},
year = {2009},
volume = {131},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ja900946h},
number = {11},
pages = {3802--3803},
doi = {10.1021/ja900946h}
}
Cite this
MLA
Copy
Gourdet, Benoit, and Hon Wai Lam. “Stereoselective Synthesis of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation of Ynamides.” Journal of the American Chemical Society, vol. 131, no. 11, Mar. 2009, pp. 3802-3803. https://doi.org/10.1021/ja900946h.