Journal of the American Chemical Society

, том 131 , издание 27 , страницы 9482-9483

Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes

Тип публикации: Journal Article

Дата публикации: 2009-06-17

American Chemical Society (ACS)

Journal of the American Chemical Society

scimago Q1

wos Q1

БС1

SJR: 5.489

CiteScore: 24.4

Impact factor: 15.6

ISSN: 00027863, 15205126

DOI: 10.1021/ja902526k

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PubMed ID: 19583431

General Chemistry

Catalysis

Biochemistry

Colloid and Surface Chemistry

Краткое описание

We report the synthesis of several unique, boron-rich pincer complexes derived from m-carborane. The SeBSe and SBS pincer ligands can be synthesized via two independent synthetic routes and are metalated with Pd(II). These structures represent unique coordinating motifs, each with a Pd-B(2) bond chelated by two thio- or selenoether ligands. This class of structures serves as the first example of boron-metal pincer complexes and possesses several interesting electronic properties imposed by the m-carborane cage.

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Spokoyny A. M. et al. Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes // Journal of the American Chemical Society. 2009. Vol. 131. No. 27. pp. 9482-9483.

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Spokoyny A. M., Reuter M. A., Stern C., Ratner M. A., SEIDEMAN T., Mirkin C. A. Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes // Journal of the American Chemical Society. 2009. Vol. 131. No. 27. pp. 9482-9483.

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TY - JOUR

DO - 10.1021/ja902526k

UR - https://doi.org/10.1021/ja902526k

TI - Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes

T2 - Journal of the American Chemical Society

AU - Spokoyny, Alexander M

AU - Reuter, M. A.

AU - Stern, Charlotte

AU - Ratner, Mark A

AU - SEIDEMAN, TAMAR

AU - Mirkin, Chad A.

PY - 2009

DA - 2009/06/17

PB - American Chemical Society (ACS)

SP - 9482-9483

IS - 27

VL - 131

PMID - 19583431

SN - 0002-7863

SN - 1520-5126

ER -

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@article{2009_Spokoyny,

author = {Alexander M Spokoyny and M. A. Reuter and Charlotte Stern and Mark A Ratner and TAMAR SEIDEMAN and Chad A. Mirkin},

title = {Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes},

journal = {Journal of the American Chemical Society},

year = {2009},

volume = {131},

publisher = {American Chemical Society (ACS)},

month = {jun},

url = {https://doi.org/10.1021/ja902526k},

number = {27},

pages = {9482--9483},

doi = {10.1021/ja902526k}

}

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Spokoyny, Alexander M., et al. “Carborane-Based Pincers: Synthesis and Structure of SeBSe and SBS Pd(II) Complexes.” Journal of the American Chemical Society, vol. 131, no. 27, Jun. 2009, pp. 9482-9483. https://doi.org/10.1021/ja902526k.