N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds
Publication type: Journal Article
Publication date: 2009-09-17
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
19807174
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
An intramolecular N-heterocyclic carbene (NHC)-catalyzed hydroacylation of unactivated double bonds is reported. Systematic variation of the catalyst structure revealed an N-mesitylthiazolylidene annulated with a seven-membered ring to be especially reactive. This NHC enables a unique C-C bond-forming reaction to afford substituted chroman-4-ones in moderate to excellent yields, even ones containing all-carbon quaternary centers.
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Metrics
209
Total citations:
209
Citations from 2025:
3
(1.44%)
Cite this
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MLA
Cite this
GOST
Copy
Hirano K. et al. N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds // Journal of the American Chemical Society. 2009. Vol. 131. No. 40. pp. 14190-14191.
GOST all authors (up to 50)
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Hirano K., Biju A., Piel I., Glorius F. N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds // Journal of the American Chemical Society. 2009. Vol. 131. No. 40. pp. 14190-14191.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja906361g
UR - https://doi.org/10.1021/ja906361g
TI - N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds
T2 - Journal of the American Chemical Society
AU - Hirano, Keiichi
AU - Biju, A.T
AU - Piel, Isabel
AU - Glorius, Frank
PY - 2009
DA - 2009/09/17
PB - American Chemical Society (ACS)
SP - 14190-14191
IS - 40
VL - 131
PMID - 19807174
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Hirano,
author = {Keiichi Hirano and A.T Biju and Isabel Piel and Frank Glorius},
title = {N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds},
journal = {Journal of the American Chemical Society},
year = {2009},
volume = {131},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja906361g},
number = {40},
pages = {14190--14191},
doi = {10.1021/ja906361g}
}
Cite this
MLA
Copy
Hirano, Keiichi, et al. “N-Heterocyclic Carbene-Catalyzed Hydroacylation of Unactivated Double Bonds.” Journal of the American Chemical Society, vol. 131, no. 40, Sep. 2009, pp. 14190-14191. https://doi.org/10.1021/ja906361g.