Journal of the American Chemical Society, volume 131, issue 50, pages 18036-18037
Direct observation of a photoinduced nonstabilized nitrile imine structure in the solid state.
Publication type: Journal Article
Publication date: 2009-11-24
Quartile SCImago
Q1
Quartile WOS
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
PubMed ID:
19928921
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
We report the direct observation of a bent geometry for a nonstabilized nitrile imine in a metal-coordination crystal. The photoinduced tetrazole ring rupture to release N(2) appears to depend on the size of voids around the N(3)-N(4) bond in the crystal lattice. We further observed the selective formation of the 1,3-addition product when a reactive nitrile imine was photogenerated in water. Overall, the bent nitrile imine geometry agrees with the 1,3-dipolar structure, a transient reactive species that mediates the photoinduced 1,3-dipolar cycloaddition in the aqueous medium.
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GOST
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Zheng S. et al. Direct observation of a photoinduced nonstabilized nitrile imine structure in the solid state. // Journal of the American Chemical Society. 2009. Vol. 131. No. 50. pp. 18036-18037.
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Zheng S., Wang Y., Yu Z., Lin Q., Coppens P. Direct observation of a photoinduced nonstabilized nitrile imine structure in the solid state. // Journal of the American Chemical Society. 2009. Vol. 131. No. 50. pp. 18036-18037.
Cite this
RIS
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TY - JOUR
DO - 10.1021/ja9094523
UR - https://doi.org/10.1021/ja9094523
TI - Direct observation of a photoinduced nonstabilized nitrile imine structure in the solid state.
T2 - Journal of the American Chemical Society
AU - Wang, Yizhong
AU - Coppens, Philip
AU - Zheng, Shao-Liang
AU - Yu, Zhipeng
AU - Lin, Qing
PY - 2009
DA - 2009/11/24
PB - American Chemical Society (ACS)
SP - 18036-18037
IS - 50
VL - 131
PMID - 19928921
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex
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@article{2009_Zheng,
author = {Yizhong Wang and Philip Coppens and Shao-Liang Zheng and Zhipeng Yu and Qing Lin},
title = {Direct observation of a photoinduced nonstabilized nitrile imine structure in the solid state.},
journal = {Journal of the American Chemical Society},
year = {2009},
volume = {131},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja9094523},
number = {50},
pages = {18036--18037},
doi = {10.1021/ja9094523}
}
Cite this
MLA
Copy
Zheng, Shao-Liang, et al. “Direct observation of a photoinduced nonstabilized nitrile imine structure in the solid state..” Journal of the American Chemical Society, vol. 131, no. 50, Nov. 2009, pp. 18036-18037. https://doi.org/10.1021/ja9094523.