,  том 118 ,  издание 2 ,  страницы 437-439

Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution:  New Evidence for Polar Interactions

Тип публикации: Journal Article
Дата публикации: 1996-01-01
SCImago Q1
Tоп 10% SCImago
WOS Q1
БС1
SJR: 5.491
CiteScore: 22
Impact factor: 16.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Absolute rate constants are reported for the addition of the methyl radical to 20 monosubstituted and 1,1-disubstituted alkenes at room temperature in liquid solution. They increase with increasing exothermicity of the addition and are enhanced by strong nucleophilic polar effects for electron-deficient alkenes. This agrees with conclusions derived from earlier relative rate data but disagrees with a general insignificance of polar effects predicted by ab initio calculations.
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ГОСТ |
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Zytowski T., Fischer H. Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution: New Evidence for Polar Interactions // Journal of the American Chemical Society. 1996. Vol. 118. No. 2. pp. 437-439.
ГОСТ со всеми авторами (до 50) Скопировать
Zytowski T., Fischer H. Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution: New Evidence for Polar Interactions // Journal of the American Chemical Society. 1996. Vol. 118. No. 2. pp. 437-439.
RIS |
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TY - JOUR
DO - 10.1021/ja953085q
UR - https://doi.org/10.1021/ja953085q
TI - Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution: New Evidence for Polar Interactions
T2 - Journal of the American Chemical Society
AU - Zytowski, Torsten
AU - Fischer, Hanns
PY - 1996
DA - 1996/01/01
PB - American Chemical Society (ACS)
SP - 437-439
IS - 2
VL - 118
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{1996_Zytowski,
author = {Torsten Zytowski and Hanns Fischer},
title = {Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution: New Evidence for Polar Interactions},
journal = {Journal of the American Chemical Society},
year = {1996},
volume = {118},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ja953085q},
number = {2},
pages = {437--439},
doi = {10.1021/ja953085q}
}
MLA
Цитировать
Zytowski, Torsten, and Hanns Fischer. “Absolute Rate Constants for the Addition of Methyl Radicals to Alkenes in Solution: New Evidence for Polar Interactions.” Journal of the American Chemical Society, vol. 118, no. 2, Jan. 1996, pp. 437-439. https://doi.org/10.1021/ja953085q.
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