Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies
Тип публикации: Journal Article
Дата публикации: 1997-09-01
scimago Q1
Tоп 10% SciMago
wos Q1
white level БС1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Photochemical reaction of Ru(PP3)H2 (PP3 = P(CH2CH2PPh2)3) in THF under a rigorously inert atmosphere yields the cyclometalated complex Ru[(Ph2PCH2CH2)2P(CH2CH2PPhC6H4)]H. The latter is converted back to Ru(PP3)H2 under H2 and reacts even with traces of N2 to yield Ru(PP3)(N2). The dinitrogen complex may be synthesized directly by a number of methods. NMR spectroscopy shows that photolysis of Ru(PP3)H2 under C2H4 and CO yields Ru(PP3)(C2H4) and Ru(PP3)(CO), respectively. Photolysis of Ru(PP3)H2 with HSiEt3 in THF yields Ru(PP3)(SiEt3)H, while photolysis in mixtures of THF and benzene at low temperature yields Ru(PP3)(Ph)H. The latter is also generated by reduction of Ru(PP3)Cl2 in the presence of benzene. Os(PP3)(Ph)H is formed either by photolysis of Os(PP3)H2 or by reduction of Os(PP3)Cl2 in the presence of benzene. Irradiation of Os(PP3)H2 in THF or THF/hexane mixtures initially yields the THF C−H activation product, Os(PP3)(2-C4H7O)H. This complex is also generated by reduction of Os(PP3)Cl2 with sodi...
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Osman R. et al. Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies // Journal of the American Chemical Society. 1997. Vol. 119. No. 36. pp. 8459-8473.
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Osman R., PATTISON D. I., Perutz R. N., Bianchini C., Casares J. A., Peruzzini M. Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies // Journal of the American Chemical Society. 1997. Vol. 119. No. 36. pp. 8459-8473.
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TY - JOUR
DO - 10.1021/ja963797w
UR - https://doi.org/10.1021/ja963797w
TI - Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies
T2 - Journal of the American Chemical Society
AU - Osman, Robert
AU - PATTISON, David I.
AU - Perutz, Robin N.
AU - Bianchini, Claudio
AU - Casares, Juan A
AU - Peruzzini, Maurizio
PY - 1997
DA - 1997/09/01
PB - American Chemical Society (ACS)
SP - 8459-8473
IS - 36
VL - 119
SN - 0002-7863
SN - 1520-5126
ER -
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@article{1997_Osman,
author = {Robert Osman and David I. PATTISON and Robin N. Perutz and Claudio Bianchini and Juan A Casares and Maurizio Peruzzini},
title = {Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies},
journal = {Journal of the American Chemical Society},
year = {1997},
volume = {119},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ja963797w},
number = {36},
pages = {8459--8473},
doi = {10.1021/ja963797w}
}
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MLA
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Osman, Robert, et al. “Photochemistry of M(PP3)H2 (M = Ru, Os; PP3 = P(CH2CH2PPh2)3): Preparative, NMR, and Time-Resolved Studies.” Journal of the American Chemical Society, vol. 119, no. 36, Sep. 1997, pp. 8459-8473. https://doi.org/10.1021/ja963797w.
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