Redox, Magnetic, and Structural Properties of 1,3,2-Dithiazolyl Radicals. A Case Study on the Ternary Heterocycle S3N5C4
T. M. Barclay
1
,
A. W. Cordes
1
,
N A George
1
,
R. C. Haddon
1
,
M.E. Itkis
1
,
M S Mashuta
1
,
R. T. Oakley
1
,
G W Patenaude
1
,
R. W. Reed
1
,
J. F. Richardson
1
,
H. Zhang
1
Publication type: Journal Article
Publication date: 1998-01-01
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The characterization of the heterocyclic radical 1,2,5-thiadiazolo[3,4-b]-1,3,2-dithiazolo[3,4-b]pyrazin-2-yl (TDP-DTA) is described. The compound is prepared by treatment of 5,6-dithiolo-1,2,5-thiadiazolo[3,4-b]pyrazine with S3N3Cl3 and purified by fractional sublimation in vacuo. The results of cyclic voltammetry and ESR analysis of TDP-DTA and related heterocyclic dithiazolyls indicate that the spin distributions and donor/acceptor properties of these radicals are extremely sensitive to the nature of the 4,5-substituents. The crystal structure of TDP-DTA has been determined at two temperatures. At 293 K, the crystals are triclinic, space group P1, with a = 4.4456(8), b = 8.407(2), c = 9.671(3) A, α = 71.34(2), β = 89.28(2), γ = 87.80(2)°, Z = 2 (for C4N5S3); at 150 K the crystals are triclinic, space group P1, with a = 7.489(7), b = 9.593(4), c = 10.759(6) A, α = 65.77(4), β = 74.10(6), γ = 74.64(6)°, Z = 2 (for C8N10S6). At 293 K the structure consists of ribbons of TDP-DTA radicals packed in a slip...
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Barclay T. M. et al. Redox, Magnetic, and Structural Properties of 1,3,2-Dithiazolyl Radicals. A Case Study on the Ternary Heterocycle S3N5C4 // Journal of the American Chemical Society. 1998. Vol. 120. No. 2. pp. 352-360.
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Barclay T. M., Cordes A. W., George N. A., Haddon R. C., Itkis M., Mashuta M. S., Oakley R. T., Patenaude G. W., Reed R. W., Richardson J. F., Zhang H. Redox, Magnetic, and Structural Properties of 1,3,2-Dithiazolyl Radicals. A Case Study on the Ternary Heterocycle S3N5C4 // Journal of the American Chemical Society. 1998. Vol. 120. No. 2. pp. 352-360.
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TY - JOUR
DO - 10.1021/ja973338a
UR - https://doi.org/10.1021/ja973338a
TI - Redox, Magnetic, and Structural Properties of 1,3,2-Dithiazolyl Radicals. A Case Study on the Ternary Heterocycle S3N5C4
T2 - Journal of the American Chemical Society
AU - Barclay, T. M.
AU - Cordes, A. W.
AU - George, N A
AU - Haddon, R. C.
AU - Itkis, M.E.
AU - Mashuta, M S
AU - Oakley, R. T.
AU - Patenaude, G W
AU - Reed, R. W.
AU - Richardson, J. F.
AU - Zhang, H.
PY - 1998
DA - 1998/01/01
PB - American Chemical Society (ACS)
SP - 352-360
IS - 2
VL - 120
SN - 0002-7863
SN - 1520-5126
ER -
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@article{1998_Barclay,
author = {T. M. Barclay and A. W. Cordes and N A George and R. C. Haddon and M.E. Itkis and M S Mashuta and R. T. Oakley and G W Patenaude and R. W. Reed and J. F. Richardson and H. Zhang},
title = {Redox, Magnetic, and Structural Properties of 1,3,2-Dithiazolyl Radicals. A Case Study on the Ternary Heterocycle S3N5C4},
journal = {Journal of the American Chemical Society},
year = {1998},
volume = {120},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ja973338a},
number = {2},
pages = {352--360},
doi = {10.1021/ja973338a}
}
Cite this
MLA
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Barclay, T. M., et al. “Redox, Magnetic, and Structural Properties of 1,3,2-Dithiazolyl Radicals. A Case Study on the Ternary Heterocycle S3N5C4.” Journal of the American Chemical Society, vol. 120, no. 2, Jan. 1998, pp. 352-360. https://doi.org/10.1021/ja973338a.