Synthesis and Reactivity of a Stable Silylene
Publication type: Journal Article
Publication date: 1998-11-25
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The synthesis and several reactions of the stable silylene 1 (1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2-diazasilol-2-ylidene) are described. X-ray crystal structures are given for two intermediates in the synthesis of 1, the diimine 7 and its dilithium salt 8, and for a byproduct, the spiro compound 10. 1 reacts with ethanol and water by inserting into the O−H bond, and with iodomethane by insertion into the C−I bond. The silanol from reaction of 1 with water condenses to a disiloxane, 13. From 1 and sulfur and selenium, cyclic compounds containing Si2E2 rings are obtained (E = S or Se). Crystal structures are presented for disiloxane 13 and for the sulfur and selenium cycloadducts, 15 and 17.
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188
Total citations:
188
Citations from 2025:
2
(1.06%)
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MLA
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GOST
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Haaf M. et al. Synthesis and Reactivity of a Stable Silylene // Journal of the American Chemical Society. 1998. Vol. 120. No. 49. pp. 12714-12719.
GOST all authors (up to 50)
Copy
Haaf M., Schmiedl A., Schmedake T., Powell D. W., Millevolte A. J., Denk M., West R. Synthesis and Reactivity of a Stable Silylene // Journal of the American Chemical Society. 1998. Vol. 120. No. 49. pp. 12714-12719.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja9733999
UR - https://doi.org/10.1021/ja9733999
TI - Synthesis and Reactivity of a Stable Silylene
T2 - Journal of the American Chemical Society
AU - Haaf, Michael
AU - Schmiedl, Andreas
AU - Schmedake, T.A.
AU - Powell, Douglas W.
AU - Millevolte, Anthony J.
AU - Denk, Michael
AU - West, Robert
PY - 1998
DA - 1998/11/25
PB - American Chemical Society (ACS)
SP - 12714-12719
IS - 49
VL - 120
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1998_Haaf,
author = {Michael Haaf and Andreas Schmiedl and T.A. Schmedake and Douglas W. Powell and Anthony J. Millevolte and Michael Denk and Robert West},
title = {Synthesis and Reactivity of a Stable Silylene},
journal = {Journal of the American Chemical Society},
year = {1998},
volume = {120},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/ja9733999},
number = {49},
pages = {12714--12719},
doi = {10.1021/ja9733999}
}
Cite this
MLA
Copy
Haaf, Michael, et al. “Synthesis and Reactivity of a Stable Silylene.” Journal of the American Chemical Society, vol. 120, no. 49, Nov. 1998, pp. 12714-12719. https://doi.org/10.1021/ja9733999.