Journal of the American Chemical Society, volume 120, issue 19, pages 4690-4698
Mechanistic Aspects of the Copolymerization of CO2 and Epoxides by Soluble Zinc Bis(phenoxide) Catalysts as Revealed by Their Cadmium Analogues
1
Contribution from the Department of Chemistry, Texas A&M University, P.O. Box 300012, College Station, Texas 77842
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Publication type: Journal Article
Publication date: 1998-04-29
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A family of monomeric cadmium(II) phenoxides of the general formula Cd(O-2,6-R2C6H3)2(base)2-3 [R = Ph, tBu, Me; base = THF, THT, pyridine, propylene carbonate] has been synthesized. Determination of the solid-state structures of all complexes have uncovered a variety of geometries ranging from the expected distorted tetrahedral to square planar to trigonal bipyramidal, depending upon the identity of the phenoxide substituents and of the base ligands. By utilizing multinuclear NMR techniques available to cadmium, particularly 113Cd NMR, it was possible to discover the identities of these complexes in solution. Reactivities of these complexes with the small molecules CO2, COS, and CS2 were also carried out. While CO2 showed no reactivity with the sterically encumbered Cd(II) bis(phenoxides), insertion was observed spectroscopically to occur for COS and CS2. The product of CS2 insertion was isolated and characterized and found to be a dimeric xanthate complex, [Cd(S2CO-2,6-Ph2C6H3)]2[μ-O-2,6-Ph2C6H3]2. Thes...
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Citations by publishers
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5
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5
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15
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25
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35
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Darensbourg D. J. et al. Mechanistic Aspects of the Copolymerization of CO2 and Epoxides by Soluble Zinc Bis(phenoxide) Catalysts as Revealed by Their Cadmium Analogues // Journal of the American Chemical Society. 1998. Vol. 120. No. 19. pp. 4690-4698.
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Darensbourg D. J., Niezgoda S. A., Draper J. D., Reibenspies J. H. Mechanistic Aspects of the Copolymerization of CO2 and Epoxides by Soluble Zinc Bis(phenoxide) Catalysts as Revealed by Their Cadmium Analogues // Journal of the American Chemical Society. 1998. Vol. 120. No. 19. pp. 4690-4698.
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TY - JOUR
DO - 10.1021/ja9801487
UR - https://doi.org/10.1021/ja9801487
TI - Mechanistic Aspects of the Copolymerization of CO2 and Epoxides by Soluble Zinc Bis(phenoxide) Catalysts as Revealed by Their Cadmium Analogues
T2 - Journal of the American Chemical Society
AU - Niezgoda, S A
AU - Draper, J D
AU - Reibenspies, J. H.
AU - Darensbourg, Donald J.
PY - 1998
DA - 1998/04/29 00:00:00
PB - American Chemical Society (ACS)
SP - 4690-4698
IS - 19
VL - 120
SN - 0002-7863
SN - 1520-5126
ER -
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@article{1998_Darensbourg,
author = {S A Niezgoda and J D Draper and J. H. Reibenspies and Donald J. Darensbourg},
title = {Mechanistic Aspects of the Copolymerization of CO2 and Epoxides by Soluble Zinc Bis(phenoxide) Catalysts as Revealed by Their Cadmium Analogues},
journal = {Journal of the American Chemical Society},
year = {1998},
volume = {120},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/ja9801487},
number = {19},
pages = {4690--4698},
doi = {10.1021/ja9801487}
}
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Darensbourg, Donald J., et al. “Mechanistic Aspects of the Copolymerization of CO2 and Epoxides by Soluble Zinc Bis(phenoxide) Catalysts as Revealed by Their Cadmium Analogues.” Journal of the American Chemical Society, vol. 120, no. 19, Apr. 1998, pp. 4690-4698. https://doi.org/10.1021/ja9801487.