Journal of the American Chemical Society, volume 121, issue 4, pages 791-799

A Recyclable Ru-Based Metathesis Catalyst

Jason S Kingsbury ¹

Joseph P. A. Harrity ¹

Peter J Bonitatebus ¹

Amir H. Hoveyda ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Contribution from the Department of Chemistry, Merkert Chemistry Center, Boston College, Chestnut Hill, Massachusetts 02467 |

Publication type: Journal Article

Publication date: 1999-01-15

American Chemical Society (ACS)

Journal: Journal of the American Chemical Society

scimago Q1

SJR: 5.489

CiteScore: 24.4

Impact factor: 14.4

ISSN: 00027863, 15205126

DOI: 10.1021/ja983222u

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General Chemistry

Catalysis

Biochemistry

Colloid and Surface Chemistry

Abstract

A Ru carbene (8, Scheme 2) that contains an internal metal−oxygen chelate is an active metathesis catalyst and is readily obtained by the sequential treatment of Cl2Ru(PPh3)3 with (2-isopropoxyphenyl)diazomethane and PCy3. This Ru-carbene complex offers excellent stability to air and moisture and can be recycled in high yield by silica gel column chromatography. The structures of this and related complexes have been unambiguously established by NMR and single-crystal X-ray diffraction studies.

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Cite this

GOST |

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GOST Copy

Kingsbury J. S. et al. A Recyclable Ru-Based Metathesis Catalyst // Journal of the American Chemical Society. 1999. Vol. 121. No. 4. pp. 791-799.

GOST all authors (up to 50) Copy

Kingsbury J. S., Harrity J. P. A., Bonitatebus P. J., Hoveyda A. H. A Recyclable Ru-Based Metathesis Catalyst // Journal of the American Chemical Society. 1999. Vol. 121. No. 4. pp. 791-799.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/ja983222u

UR - https://doi.org/10.1021/ja983222u

TI - A Recyclable Ru-Based Metathesis Catalyst

T2 - Journal of the American Chemical Society

AU - Kingsbury, Jason S

AU - Harrity, Joseph P. A.

AU - Bonitatebus, Peter J

AU - Hoveyda, Amir H.

PY - 1999

DA - 1999/01/15

PB - American Chemical Society (ACS)

SP - 791-799

IS - 4

VL - 121

SN - 0002-7863

SN - 1520-5126

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{1999_Kingsbury,

author = {Jason S Kingsbury and Joseph P. A. Harrity and Peter J Bonitatebus and Amir H. Hoveyda},

title = {A Recyclable Ru-Based Metathesis Catalyst},

journal = {Journal of the American Chemical Society},

year = {1999},

volume = {121},

publisher = {American Chemical Society (ACS)},

month = {jan},

url = {https://doi.org/10.1021/ja983222u},

number = {4},

pages = {791--799},

doi = {10.1021/ja983222u}

}

MLA

Cite this

MLA Copy

Kingsbury, Jason S., et al. “A Recyclable Ru-Based Metathesis Catalyst.” Journal of the American Chemical Society, vol. 121, no. 4, Jan. 1999, pp. 791-799. https://doi.org/10.1021/ja983222u.

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Publisher

American Chemical Society (ACS)

Journal

Journal of the American Chemical Society

scimago Q1

SJR

5.489

CiteScore

24.4

Impact factor

14.4

ISSN

00027863 (Print)

15205126 (Electronic)