том 121 издание 18 страницы 4369-4378

Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers

Тип публикацииJournal Article
Дата публикации1999-04-27
scimago Q1
wos Q1
БС1
SJR5.489
CiteScore24.4
Impact factor15.6
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
A general method for the palladium-catalyzed formation of diaryl ethers is described. Electron-rich, bulky aryldialkylphosphine ligands, in which the two alkyl groups are either tert-butyl or 1-adamantyl, are the key to the success of the transformation. A wide range of electron-deficient, electronically neutral and electron-rich aryl bromides, chlorides, and triflates can be combined with a variety of phenols with the use of sodium hydride or potassium phosphate as base in toluene at 100 °C. The bulky yet basic nature of the phosphine ligand is thought to be responsible for increasing the rate of reductive elimination of the diaryl ether from palladium.
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ГОСТ |
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Aranyos A. et al. Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers // Journal of the American Chemical Society. 1999. Vol. 121. No. 18. pp. 4369-4378.
ГОСТ со всеми авторами (до 50) Скопировать
Aranyos A., Old D. W., Kiyomori A., John A. Wolfe (2) J. S., Sadighi J. P., Buchwald S. L. Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers // Journal of the American Chemical Society. 1999. Vol. 121. No. 18. pp. 4369-4378.
RIS |
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TY - JOUR
DO - 10.1021/ja990324r
UR - https://pubs.acs.org/doi/10.1021/ja990324r
TI - Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers
T2 - Journal of the American Chemical Society
AU - Aranyos, Attila
AU - Old, David W.
AU - Kiyomori, Ayumu
AU - John A. Wolfe (2), JOHN S.
AU - Sadighi, Joseph P.
AU - Buchwald, Stephen L.
PY - 1999
DA - 1999/04/27
PB - American Chemical Society (ACS)
SP - 4369-4378
IS - 18
VL - 121
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{1999_Aranyos,
author = {Attila Aranyos and David W. Old and Ayumu Kiyomori and JOHN S. John A. Wolfe (2) and Joseph P. Sadighi and Stephen L. Buchwald},
title = {Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers},
journal = {Journal of the American Chemical Society},
year = {1999},
volume = {121},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://pubs.acs.org/doi/10.1021/ja990324r},
number = {18},
pages = {4369--4378},
doi = {10.1021/ja990324r}
}
MLA
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Aranyos, Attila, et al. “Novel Electron-Rich Bulky Phosphine Ligands Facilitate the Palladium-Catalyzed Preparation of Diaryl Ethers.” Journal of the American Chemical Society, vol. 121, no. 18, Apr. 1999, pp. 4369-4378. https://pubs.acs.org/doi/10.1021/ja990324r.