Ti2Nb6O12, a Novel Niobium Oxide Cluster Compound with “Chevrel Phase” Intercluster Connectivity Type
Publication type: Journal Article
Publication date: 1999-07-01
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The niobium oxide cluster compound Ti2Nb6O12 was synthesized from NbO, NbO2, and TiO2 in the presence of NaF melt at 950 °C. It crystallizes in an original structure type based on octahedral cluster units (Nb6 ) . The clusters connect to each other through outer−inner linkages to form a three-dimensional framework containing cubeoctahedral cavities. The cluster connectivity pattern in Ti2Nb6O12 and intercluster metal−metal distances are similar to those found in the “Chevrel phases”. The Ti4+ ions have a distorted octahedral environment formed by the oxide ligands belonging to the clusters. Band structure calculations indicate that the lowest unoccupied band in Ti2Nb6O12 resembles the conduction band in the superconducting “Chevrel phases”.
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Total citations:
18
Citations from 2025:
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(5.56%)
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GOST
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Anokhina E. V. et al. Ti2Nb6O12, a Novel Niobium Oxide Cluster Compound with “Chevrel Phase” Intercluster Connectivity Type // Journal of the American Chemical Society. 1999. Vol. 121. No. 29. pp. 6827-6833.
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Anokhina E. V., Essig M. W., Day C. S., Lachgar A. Ti2Nb6O12, a Novel Niobium Oxide Cluster Compound with “Chevrel Phase” Intercluster Connectivity Type // Journal of the American Chemical Society. 1999. Vol. 121. No. 29. pp. 6827-6833.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ja990759e
UR - https://doi.org/10.1021/ja990759e
TI - Ti2Nb6O12, a Novel Niobium Oxide Cluster Compound with “Chevrel Phase” Intercluster Connectivity Type
T2 - Journal of the American Chemical Society
AU - Anokhina, Ekaterina V
AU - Essig, Michael W
AU - Day, Cynthia S
AU - Lachgar, Abdessadek
PY - 1999
DA - 1999/07/01
PB - American Chemical Society (ACS)
SP - 6827-6833
IS - 29
VL - 121
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{1999_Anokhina,
author = {Ekaterina V Anokhina and Michael W Essig and Cynthia S Day and Abdessadek Lachgar},
title = {Ti2Nb6O12, a Novel Niobium Oxide Cluster Compound with “Chevrel Phase” Intercluster Connectivity Type},
journal = {Journal of the American Chemical Society},
year = {1999},
volume = {121},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ja990759e},
number = {29},
pages = {6827--6833},
doi = {10.1021/ja990759e}
}
Cite this
MLA
Copy
Anokhina, Ekaterina V., et al. “Ti2Nb6O12, a Novel Niobium Oxide Cluster Compound with “Chevrel Phase” Intercluster Connectivity Type.” Journal of the American Chemical Society, vol. 121, no. 29, Jul. 1999, pp. 6827-6833. https://doi.org/10.1021/ja990759e.