Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron
Mingkang Zhou
1
,
Kaidi Li
1
,
Dongping Chen
1
,
RONGHUA XU
1
,
Guangqing Xu
1, 2
,
Wenjun Tang
1, 2, 3
2
NingBo Zejun Pharmaceutical Technology Co., Ltd, Hangzhou Bay New District, Ningbo 315336, China
|
Publication type: Journal Article
Publication date: 2020-05-27
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
32459089
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
We herein report a general, practical, and highly efficient method for asymmetric synthesis of a wide range of chiral vicinal diamines via reductive coupling of imines templated by chiral diboron. The protocol features high enantioselectivity and stereospecificity, mild reaction conditions, simple operating procedures, use of readily available starting materials, and a broad substrate scope. The method signifies the generality of diboron-enabled [3,3]-sigmatropic rearrangement.
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Metrics
70
Total citations:
70
Citations from 2025:
15
(21.43%)
Cite this
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BibTex |
MLA
Cite this
GOST
Copy
Zhou M. et al. Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron // Journal of the American Chemical Society. 2020. Vol. 142. No. 23. pp. 10337-10342.
GOST all authors (up to 50)
Copy
Zhou M., Li K., Chen D., XU R., Xu G., Tang W. Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron // Journal of the American Chemical Society. 2020. Vol. 142. No. 23. pp. 10337-10342.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.0c04558
UR - https://doi.org/10.1021/jacs.0c04558
TI - Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron
T2 - Journal of the American Chemical Society
AU - Zhou, Mingkang
AU - Li, Kaidi
AU - Chen, Dongping
AU - XU, RONGHUA
AU - Xu, Guangqing
AU - Tang, Wenjun
PY - 2020
DA - 2020/05/27
PB - American Chemical Society (ACS)
SP - 10337-10342
IS - 23
VL - 142
PMID - 32459089
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Zhou,
author = {Mingkang Zhou and Kaidi Li and Dongping Chen and RONGHUA XU and Guangqing Xu and Wenjun Tang},
title = {Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron},
journal = {Journal of the American Chemical Society},
year = {2020},
volume = {142},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/jacs.0c04558},
number = {23},
pages = {10337--10342},
doi = {10.1021/jacs.0c04558}
}
Cite this
MLA
Copy
Zhou, Mingkang, et al. “Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron.” Journal of the American Chemical Society, vol. 142, no. 23, May. 2020, pp. 10337-10342. https://doi.org/10.1021/jacs.0c04558.