Carbonylative C–C Bond Activation of Aminocyclopropanes Using a Temporary Directing Group Strategy
Gang Wei Wang
1
,
Olga O Sokolova
1
,
Tom A Young
2
,
Ektor M S Christodoulou
1
,
Craig P Butts
1
,
John Eric Bower
1, 3
Publication type: Journal Article
Publication date: 2020-10-30
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
33125219
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Temporary directing groups (TDGs) underpin a range of C-C bond activation methodologies; however, the use of TDGs for the regiocontrolled activation of cyclopropane C-C bonds is underdeveloped. In this report, we show how an unusual ring contraction process can be harnessed for TDG-based carbonylative C-C bond activations of cyclopropanes. The method involves the transient installation of an isocyanate-derived TDG, rather than relying on carbonyl condensation events as used in previous TDG-enabled C-C bond activations.
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Metrics
29
Total citations:
29
Citations from 2024:
9
(31%)
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MLA
Cite this
GOST
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Wang G. W. et al. Carbonylative C–C Bond Activation of Aminocyclopropanes Using a Temporary Directing Group Strategy // Journal of the American Chemical Society. 2020. Vol. 142. No. 45. pp. 19006-19011.
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Wang G. W., Sokolova O. O., Young T. A., Christodoulou E. M. S., Butts C. P., Bower J. E. Carbonylative C–C Bond Activation of Aminocyclopropanes Using a Temporary Directing Group Strategy // Journal of the American Chemical Society. 2020. Vol. 142. No. 45. pp. 19006-19011.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.0c08973
UR - https://doi.org/10.1021/jacs.0c08973
TI - Carbonylative C–C Bond Activation of Aminocyclopropanes Using a Temporary Directing Group Strategy
T2 - Journal of the American Chemical Society
AU - Wang, Gang Wei
AU - Sokolova, Olga O
AU - Young, Tom A
AU - Christodoulou, Ektor M S
AU - Butts, Craig P
AU - Bower, John Eric
PY - 2020
DA - 2020/10/30
PB - American Chemical Society (ACS)
SP - 19006-19011
IS - 45
VL - 142
PMID - 33125219
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2020_Wang,
author = {Gang Wei Wang and Olga O Sokolova and Tom A Young and Ektor M S Christodoulou and Craig P Butts and John Eric Bower},
title = {Carbonylative C–C Bond Activation of Aminocyclopropanes Using a Temporary Directing Group Strategy},
journal = {Journal of the American Chemical Society},
year = {2020},
volume = {142},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/jacs.0c08973},
number = {45},
pages = {19006--19011},
doi = {10.1021/jacs.0c08973}
}
Cite this
MLA
Copy
Wang, Gang Wei, et al. “Carbonylative C–C Bond Activation of Aminocyclopropanes Using a Temporary Directing Group Strategy.” Journal of the American Chemical Society, vol. 142, no. 45, Oct. 2020, pp. 19006-19011. https://doi.org/10.1021/jacs.0c08973.