Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone
Publication type: Journal Article
Publication date: 2021-10-20
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
34669422
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Carbon dioxide (CO2) has been used as a sustainable comonomer in the synthesis of different functional polymers including polycarbonates, polyurea, and polyurethane. Until today, despite the great interest, little success has been made for incorporating CO2 into the most widely used polyethylene materials. Herein, we report the incorporation of CO2 to polyethylenes through the copolymerization of ethylene with a CO2/butadiene-derived lactone, 3-ethylidene-6-vinyltetrahydro-2H-pyran-2-one (EVP). Two-types of main-chain-functionalized polyethylenes can be synthesized through different copolymerization strategies. Palladium-catalyzed coordination/insertion copolymerization furnished polyethylenes bearing unsaturated lactones, while radical copolymerization afforded polyethylenes bearing bicyclic lactones. Modification of the polyethylene chains was successfully accomplished through Michael addition or aminolysis. This highly versatile copolymerization protocol provides access to a diverse range of polyethylene materials made from ethylene, CO2, and 1,3-butadiene.
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GOST
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Tang S., Zhao Y., Nozaki K. Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone // Journal of the American Chemical Society. 2021. Vol. 143. No. 43. pp. 17953-17957.
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Tang S., Zhao Y., Nozaki K. Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone // Journal of the American Chemical Society. 2021. Vol. 143. No. 43. pp. 17953-17957.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.1c08578
UR - https://doi.org/10.1021/jacs.1c08578
TI - Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone
T2 - Journal of the American Chemical Society
AU - Tang, Shan
AU - Zhao, Yajun
AU - Nozaki, Kyoko
PY - 2021
DA - 2021/10/20
PB - American Chemical Society (ACS)
SP - 17953-17957
IS - 43
VL - 143
PMID - 34669422
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Tang,
author = {Shan Tang and Yajun Zhao and Kyoko Nozaki},
title = {Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone},
journal = {Journal of the American Chemical Society},
year = {2021},
volume = {143},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/jacs.1c08578},
number = {43},
pages = {17953--17957},
doi = {10.1021/jacs.1c08578}
}
Cite this
MLA
Copy
Tang, Shan, et al. “Accessing Divergent Main-Chain-Functionalized Polyethylenes via Copolymerization of Ethylene with a CO2/Butadiene-Derived Lactone.” Journal of the American Chemical Society, vol. 143, no. 43, Oct. 2021, pp. 17953-17957. https://doi.org/10.1021/jacs.1c08578.