Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes
Тип публикации: Journal Article
Дата публикации: 2016-04-15
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
27070297
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The vastly increasing application of chiral Cp ligands in asymmetric catalysis results in growing demand for novel chiral Cp ligands. Herein, we report a new class of chiral Cp ligands based on 1,1'-spirobiindane, a privileged scaffold for chiral ligands and catalysts. The corresponding Rh complexes are shown to be excellent catalysts in asymmetric oxidative coupling reactions, providing axially chiral biaryls in 19-97% yields with up to 98:2 er.
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ГОСТ
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Zheng J. et al. Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes // Journal of the American Chemical Society. 2016. Vol. 138. No. 16. pp. 5242-5245.
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Zheng J., Cui W. J., Zheng C., You S. Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes // Journal of the American Chemical Society. 2016. Vol. 138. No. 16. pp. 5242-5245.
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TY - JOUR
DO - 10.1021/jacs.6b02302
UR - https://doi.org/10.1021/jacs.6b02302
TI - Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes
T2 - Journal of the American Chemical Society
AU - Zheng, Jun
AU - Cui, Wen Jun
AU - Zheng, Chao
AU - You, Shu-Li
PY - 2016
DA - 2016/04/15
PB - American Chemical Society (ACS)
SP - 5242-5245
IS - 16
VL - 138
PMID - 27070297
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{2016_Zheng,
author = {Jun Zheng and Wen Jun Cui and Chao Zheng and Shu-Li You},
title = {Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes},
journal = {Journal of the American Chemical Society},
year = {2016},
volume = {138},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/jacs.6b02302},
number = {16},
pages = {5242--5245},
doi = {10.1021/jacs.6b02302}
}
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MLA
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Zheng, Jun, et al. “Synthesis and Application of Chiral Spiro Cp Ligands in Rhodium-Catalyzed Asymmetric Oxidative Coupling of Biaryl Compounds with Alkenes.” Journal of the American Chemical Society, vol. 138, no. 16, Apr. 2016, pp. 5242-5245. https://doi.org/10.1021/jacs.6b02302.