volume 138 issue 17 pages 5547-5550

Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes

Publication typeJournal Article
Publication date2016-04-22
scimago Q1
wos Q1
SJR5.554
CiteScore22.5
Impact factor15.6
ISSN00027863, 15205126
PubMed ID:  27090215
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Cobalt-catalyzed carboxyzincation reactions employing carbon dioxide and zinc metal powder are developed. By using alkynes as substrates, regio- and stereodefined (Z)-β-zincated acrylates are provided. The corresponding alkenylzinc moiety can be converted to various substituents, affording multisubstituted acrylic acids. Furthermore, by adding electron-deficient alkene to the reaction system, the four-component coupling reactions of alkyne, alkene, CO2, and the Zn atom proceed via carboxyzincation.
Found 
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GOST Copy
Nogi K. et al. Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes // Journal of the American Chemical Society. 2016. Vol. 138. No. 17. pp. 5547-5550.
GOST all authors (up to 50) Copy
Nogi K., Fujihara T., Terao J., Tsuji Y. Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes // Journal of the American Chemical Society. 2016. Vol. 138. No. 17. pp. 5547-5550.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/jacs.6b02961
UR - https://doi.org/10.1021/jacs.6b02961
TI - Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes
T2 - Journal of the American Chemical Society
AU - Nogi, Keisuke
AU - Fujihara, Tetsuaki
AU - Terao, Jun
AU - Tsuji, Yasushi
PY - 2016
DA - 2016/04/22
PB - American Chemical Society (ACS)
SP - 5547-5550
IS - 17
VL - 138
PMID - 27090215
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2016_Nogi,
author = {Keisuke Nogi and Tetsuaki Fujihara and Jun Terao and Yasushi Tsuji},
title = {Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes},
journal = {Journal of the American Chemical Society},
year = {2016},
volume = {138},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/jacs.6b02961},
number = {17},
pages = {5547--5550},
doi = {10.1021/jacs.6b02961}
}
MLA
Cite this
MLA Copy
Nogi, Keisuke, et al. “Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes.” Journal of the American Chemical Society, vol. 138, no. 17, Apr. 2016, pp. 5547-5550. https://doi.org/10.1021/jacs.6b02961.