том 138 издание 33 страницы 10531-10538

(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center

Тип публикацииJournal Article
Дата публикации2016-08-16
scimago Q1
wos Q1
БС1
SJR5.489
CiteScore24.4
Impact factor15.6
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The first example of a transition metal (BB)-carboryne complex containing two boron atoms of the icosahedral cage connected to a single exohedral metal center (POBBOP)Ru(CO)2 (POBBOP = 1,7-OP(i-Pr)2-2,6-dehydro-m-carborane) was synthesized by double B–H activation within the strained m-carboranyl pincer framework. Theoretical calculations revealed that the unique three-membered (BB)>Ru metalacycle is formed by two bent B–Ru σ-bonds with the concomitant increase of the bond order between the two metalated boron atoms. The reactivity of the highly strained electron-rich (BB)-carboryne fragment with small molecules was probed by reactions with electrophiles. The carboryne–carboranyl transformations reported herein represent a new mode of cooperative metal–ligand reactivity of boron-based complexes.
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ГОСТ |
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Eleazer B. J. et al. (BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center // Journal of the American Chemical Society. 2016. Vol. 138. No. 33. pp. 10531-10538.
ГОСТ со всеми авторами (до 50) Скопировать
Eleazer B. J., Smith M., Popov A., Peryshkov D. V. (BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center // Journal of the American Chemical Society. 2016. Vol. 138. No. 33. pp. 10531-10538.
RIS |
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TY - JOUR
DO - 10.1021/jacs.6b05172
UR - https://doi.org/10.1021/jacs.6b05172
TI - (BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center
T2 - Journal of the American Chemical Society
AU - Eleazer, Bennett J
AU - Smith, Mark
AU - Popov, Alexey
AU - Peryshkov, Dmitry V.
PY - 2016
DA - 2016/08/16
PB - American Chemical Society (ACS)
SP - 10531-10538
IS - 33
VL - 138
PMID - 27526855
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
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BibTex (до 50 авторов) Скопировать
@article{2016_Eleazer,
author = {Bennett J Eleazer and Mark Smith and Alexey Popov and Dmitry V. Peryshkov},
title = {(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center},
journal = {Journal of the American Chemical Society},
year = {2016},
volume = {138},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/jacs.6b05172},
number = {33},
pages = {10531--10538},
doi = {10.1021/jacs.6b05172}
}
MLA
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Eleazer, Bennett J., et al. “(BB)-Carboryne Complex of Ruthenium: Synthesis by Double B–H Activation at a Single Metal Center.” Journal of the American Chemical Society, vol. 138, no. 33, Aug. 2016, pp. 10531-10538. https://doi.org/10.1021/jacs.6b05172.