American Chemical Society (ACS)
Journal of the American Chemical Society
,  том 138 ,  издание 51 ,  страницы 16592-16595

Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2-Cl–)(μ2-η2,η2-C60)2 Dimers

Тип публикации: Journal Article
Дата публикации: 2016-12-19
American Chemical Society (ACS)
scimago Q1
wos Q1
БС1
SJR: 5.489
CiteScore: 24.4
Impact factor: 15.6
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
A spin crossover phenomena is observed in an anionic (Bu4N+){Co(Ph3P)}2(μ2-Cl-)(μ2-η2,η2-C60)2·2C6H14 (1) complex in which two cobalt atoms bridge two fullerene molecules to form a dimer. The dimer has a triplet ground state with two weakly coupling Co0 atoms (S = 1/2). The spin transition realized above 150 K is accompanied by a cobalt-to-fullerene charge transfer that forms a quintet excited state with a high spin CoI (S = 1) and C60•- (S = 1/2).
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Konarev D. V. et al. Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2-Cl–)(μ2-η2,η2-C60)2 Dimers // Journal of the American Chemical Society. 2016. Vol. 138. No. 51. pp. 16592-16595.
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Konarev D. V., Khasanov S., Shestakov A. F., Ishikawa M., Otsuka A., Yamochi H., Saito G., Lyubovskaya R. N. Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2-Cl–)(μ2-η2,η2-C60)2 Dimers // Journal of the American Chemical Society. 2016. Vol. 138. No. 51. pp. 16592-16595.
RIS |
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TY - JOUR
DO - 10.1021/jacs.6b09890
UR - https://doi.org/10.1021/jacs.6b09890
TI - Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2-Cl–)(μ2-η2,η2-C60)2 Dimers
T2 - Journal of the American Chemical Society
AU - Konarev, Dmitri V.
AU - Khasanov, Salavat
AU - Shestakov, Alexander F.
AU - Ishikawa, Manabu
AU - Otsuka, Akihiro
AU - Yamochi, H.
AU - Saito, Gunzi
AU - Lyubovskaya, Rimma N.
PY - 2016
DA - 2016/12/19
PB - American Chemical Society (ACS)
SP - 16592-16595
IS - 51
VL - 138
PMID - 27936666
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2016_Konarev,
author = {Dmitri V. Konarev and Salavat Khasanov and Alexander F. Shestakov and Manabu Ishikawa and Akihiro Otsuka and H. Yamochi and Gunzi Saito and Rimma N. Lyubovskaya},
title = {Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2-Cl–)(μ2-η2,η2-C60)2 Dimers},
journal = {Journal of the American Chemical Society},
year = {2016},
volume = {138},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jacs.6b09890},
number = {51},
pages = {16592--16595},
doi = {10.1021/jacs.6b09890}
}
MLA
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Konarev, Dmitri V., et al. “Spin Crossover in Anionic Cobalt-Bridged Fullerene (Bu4N+){Co(Ph3P)}2(μ2-Cl–)(μ2-η2,η2-C60)2 Dimers.” Journal of the American Chemical Society, vol. 138, no. 51, Dec. 2016, pp. 16592-16595. https://doi.org/10.1021/jacs.6b09890.