Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal–Organic Frameworks
Publication type: Journal Article
Publication date: 2017-01-03
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
28045517
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Covalent postsynthetic modification (PSM) of metal-organic frameworks (MOFs) has attracted much attention due to the possibility of tailoring the properties of these porous materials. Schiff-base condensation between an amine and an aldehyde is one of the most common reactions in the PSM of MOFs. Here, we report the use of the spray drying technique to perform this class of organic reactions, either between discrete organic molecules or on the pore surfaces of MOFs, in a very fast (1-2 s) and continuous way. Using spray drying, we show the PSM of two MOFs, the amine-terminated UiO-66-NH2 and the aldehyde-terminated ZIF-90, achieving conversion efficiencies up to 20 and 42%, respectively. Moreover, we demonstrate that it can also be used to postsynthetically cross-link the aldehyde groups of ZIF-90 using a diamine molecule with a conversion efficiency of 70%.
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112
Total citations:
112
Citations from 2024:
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(13.39%)
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GOST
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Garzon Tovar L. et al. Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal–Organic Frameworks // Journal of the American Chemical Society. 2017. Vol. 139. No. 2. pp. 897-903.
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Garzon Tovar L., Rodríguez-Hermida S., Imaz I., Maspoch D. Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal–Organic Frameworks // Journal of the American Chemical Society. 2017. Vol. 139. No. 2. pp. 897-903.
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RIS
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TY - JOUR
DO - 10.1021/jacs.6b11240
UR - https://doi.org/10.1021/jacs.6b11240
TI - Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal–Organic Frameworks
T2 - Journal of the American Chemical Society
AU - Garzon Tovar, Luis
AU - Rodríguez-Hermida, S.
AU - Imaz, Inhar
AU - Maspoch, Daniel
PY - 2017
DA - 2017/01/03
PB - American Chemical Society (ACS)
SP - 897-903
IS - 2
VL - 139
PMID - 28045517
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Garzon Tovar,
author = {Luis Garzon Tovar and S. Rodríguez-Hermida and Inhar Imaz and Daniel Maspoch},
title = {Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal–Organic Frameworks},
journal = {Journal of the American Chemical Society},
year = {2017},
volume = {139},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jacs.6b11240},
number = {2},
pages = {897--903},
doi = {10.1021/jacs.6b11240}
}
Cite this
MLA
Copy
Garzon Tovar, Luis, et al. “Spray Drying for Making Covalent Chemistry: Postsynthetic Modification of Metal–Organic Frameworks.” Journal of the American Chemical Society, vol. 139, no. 2, Jan. 2017, pp. 897-903. https://doi.org/10.1021/jacs.6b11240.
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