Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition
Publication type: Journal Article
Publication date: 2017-04-10
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
28394586
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A discrete, dicopper μ-alkynyl complex, [Cu2(μ-η1:η1-C≡C(C6H4)CH3)DPFN]NTf2 (DPFN = 2,7-bis(fluoro-di(2-pyridyl)methyl)-1,8-naphthyridine; NTf2- = N(SO2CF3)2-), reacts with p-tolylazide to yield a dicopper complex with a symmetrically bridging 1,2,3-triazolide, [Cu2(μ-η1:η1-(1,4-bis(4-tolyl)-1,2,3-triazolide))DPFN]NTf2. This transformation exhibits bimolecular reaction kinetics and represents a key step in a proposed, bimetallic mechanism for copper-catalyzed azide-alkyne cycloaddition (CuAAC). The μ-alkynyl and μ-triazolide complexes undergo reversible redox events (by cyclic voltammetry), suggesting that a cycloaddition pathway involving mixed-valence dicopper species might also be possible. Synthesis and characterization of the mixed-valence μ-alkynyl dicopper complex, [Cu2(μ-η1:η1-C≡C(C6H4)CH3)DPFN](NTf2)2, revealed an electronic structure with an unexpected partially delocalized spin, as evidenced by electron paramagnetic resonance spectroscopy. Studies of the mixed-valence μ-alkynyl complex's reactivity suggest that a mixed-valence pathway is less likely than one involving intermediates with only copper(I).
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
2
4
6
8
10
|
|
|
Angewandte Chemie
10 publications, 7.58%
|
|
|
Angewandte Chemie - International Edition
10 publications, 7.58%
|
|
|
Journal of the American Chemical Society
9 publications, 6.82%
|
|
|
Chemistry - A European Journal
8 publications, 6.06%
|
|
|
Organometallics
7 publications, 5.3%
|
|
|
Inorganic Chemistry
6 publications, 4.55%
|
|
|
Dalton Transactions
5 publications, 3.79%
|
|
|
Journal of Catalysis
3 publications, 2.27%
|
|
|
ChemistrySelect
3 publications, 2.27%
|
|
|
Chemical Science
3 publications, 2.27%
|
|
|
Chemical Communications
3 publications, 2.27%
|
|
|
Green Chemistry
3 publications, 2.27%
|
|
|
ACS Catalysis
2 publications, 1.52%
|
|
|
Polyhedron
2 publications, 1.52%
|
|
|
ChemPhysChem
2 publications, 1.52%
|
|
|
Chemistry - An Asian Journal
2 publications, 1.52%
|
|
|
Journal of Solid State Chemistry
2 publications, 1.52%
|
|
|
Organic Letters
2 publications, 1.52%
|
|
|
Journal of Organic Chemistry
2 publications, 1.52%
|
|
|
New Journal of Chemistry
2 publications, 1.52%
|
|
|
ChemCatChem
2 publications, 1.52%
|
|
|
Chemical Society Reviews
2 publications, 1.52%
|
|
|
Chemical Reviews
1 publication, 0.76%
|
|
|
Crystals
1 publication, 0.76%
|
|
|
Australian Journal of Chemistry
1 publication, 0.76%
|
|
|
Chemistry Letters
1 publication, 0.76%
|
|
|
Chinese Journal of Organic Chemistry
1 publication, 0.76%
|
|
|
Journal of Chemical Crystallography
1 publication, 0.76%
|
|
|
Catalysis Letters
1 publication, 0.76%
|
|
|
2
4
6
8
10
|
Publishers
|
5
10
15
20
25
30
35
40
45
|
|
|
Wiley
43 publications, 32.58%
|
|
|
American Chemical Society (ACS)
35 publications, 26.52%
|
|
|
Royal Society of Chemistry (RSC)
22 publications, 16.67%
|
|
|
Elsevier
16 publications, 12.12%
|
|
|
Springer Nature
5 publications, 3.79%
|
|
|
MDPI
2 publications, 1.52%
|
|
|
Oxford University Press
2 publications, 1.52%
|
|
|
Taylor & Francis
2 publications, 1.52%
|
|
|
CSIRO Publishing
1 publication, 0.76%
|
|
|
Shanghai Institute of Organic Chemistry
1 publication, 0.76%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 0.76%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 publication, 0.76%
|
|
|
5
10
15
20
25
30
35
40
45
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
132
Total citations:
132
Citations from 2025:
16
(12.13%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Ziegler M. S. et al. Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition // Journal of the American Chemical Society. 2017. Vol. 139. No. 15. pp. 5378-5386.
GOST all authors (up to 50)
Copy
Ziegler M. S., Lakshmi K., Tilley T. D. Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition // Journal of the American Chemical Society. 2017. Vol. 139. No. 15. pp. 5378-5386.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.6b13261
UR - https://doi.org/10.1021/jacs.6b13261
TI - Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition
T2 - Journal of the American Chemical Society
AU - Ziegler, Micah S
AU - Lakshmi, K.V.
AU - Tilley, T. Don
PY - 2017
DA - 2017/04/10
PB - American Chemical Society (ACS)
SP - 5378-5386
IS - 15
VL - 139
PMID - 28394586
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Ziegler,
author = {Micah S Ziegler and K.V. Lakshmi and T. Don Tilley},
title = {Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition},
journal = {Journal of the American Chemical Society},
year = {2017},
volume = {139},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021/jacs.6b13261},
number = {15},
pages = {5378--5386},
doi = {10.1021/jacs.6b13261}
}
Cite this
MLA
Copy
Ziegler, Micah S., et al. “Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide–Alkyne Cycloaddition.” Journal of the American Chemical Society, vol. 139, no. 15, Apr. 2017, pp. 5378-5386. https://doi.org/10.1021/jacs.6b13261.