Scalable, Electrochemical Oxidation of Unactivated C–H Bonds
2
Asymchem
Life Science (Tianjin), Tianjin Economic-Technological Development Zone, Tianjin 300457, China
|
3
Discovery
Sciences, Medicine Design, Pfizer Global Research and Development, 445 Eastern Point Road, Groton, Connecticut 06340, United States
|
Publication type: Journal Article
Publication date: 2017-05-23
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
28510449
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
A practical electrochemical oxidation of unactivated C-H bonds is presented. This reaction utilizes a simple redox mediator, quinuclidine, with inexpensive carbon and nickel electrodes to selectively functionalize "deep-seated" methylene and methine moieties. The process exhibits a broad scope and good functional group compatibility. The scalability, as illustrated by a 50 g scale oxidation of sclareolide, bodes well for immediate and widespread adoption.
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424
Total citations:
424
Citations from 2025:
44
(10.38%)
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GOST
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Kawamata Yu. et al. Scalable, Electrochemical Oxidation of Unactivated C–H Bonds // Journal of the American Chemical Society. 2017. Vol. 139. No. 22. pp. 7448-7451.
GOST all authors (up to 50)
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Kawamata Yu., Yan M., Liu Z., Bao D. H., Chen J., Starr L. T., Baran P. S. Scalable, Electrochemical Oxidation of Unactivated C–H Bonds // Journal of the American Chemical Society. 2017. Vol. 139. No. 22. pp. 7448-7451.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.7b03539
UR - https://doi.org/10.1021/jacs.7b03539
TI - Scalable, Electrochemical Oxidation of Unactivated C–H Bonds
T2 - Journal of the American Chemical Society
AU - Kawamata, Yu
AU - Yan, Ming
AU - Liu, Zhiqing
AU - Bao, Deng Hui
AU - Chen, Jinshan
AU - Starr, Lauren T
AU - Baran, Phil S
PY - 2017
DA - 2017/05/23
PB - American Chemical Society (ACS)
SP - 7448-7451
IS - 22
VL - 139
PMID - 28510449
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Kawamata,
author = {Yu Kawamata and Ming Yan and Zhiqing Liu and Deng Hui Bao and Jinshan Chen and Lauren T Starr and Phil S Baran},
title = {Scalable, Electrochemical Oxidation of Unactivated C–H Bonds},
journal = {Journal of the American Chemical Society},
year = {2017},
volume = {139},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/jacs.7b03539},
number = {22},
pages = {7448--7451},
doi = {10.1021/jacs.7b03539}
}
Cite this
MLA
Copy
Kawamata, Yu., et al. “Scalable, Electrochemical Oxidation of Unactivated C–H Bonds.” Journal of the American Chemical Society, vol. 139, no. 22, May. 2017, pp. 7448-7451. https://doi.org/10.1021/jacs.7b03539.
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