Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch
Тип публикации: Journal Article
Дата публикации: 2017-12-22
scimago Q1
wos Q1
БС1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
29257859
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Ligand metathesis of Pd(II) complexes is mechanistically essential for cross-coupling. We present a study of halide→OH anion metathesis of (Ar)PdII complexes using vinylBPin as a bifunctional chemical probe with Pd(II)-dependent cross-coupling pathways. We identify the variables that profoundly impact this event and allow control to be leveraged. This then allows control of cross-coupling pathways via promotion or inhibition of organoboron transmetalation, leading to either Suzuki-Miyaura or Mizoroki-Heck products. We show how this transmetalation switch can be used to synthetic gain in a cascade cross-coupling/Diels-Alder reaction, delivering borylated or non-borylated carbocycles, including steroid-like scaffolds.
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ГОСТ
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MOLLOY J. C. et al. Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch // Journal of the American Chemical Society. 2017. Vol. 140. No. 1. pp. 126-130.
ГОСТ со всеми авторами (до 50)
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MOLLOY J. C., Seath C. P., West M. J., Mclaughlin C., Fazakerley N. J., Kennedy M. R., Nelson D. J., Watson A. J. B. Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch // Journal of the American Chemical Society. 2017. Vol. 140. No. 1. pp. 126-130.
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TY - JOUR
DO - 10.1021/jacs.7b11180
UR - https://doi.org/10.1021/jacs.7b11180
TI - Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch
T2 - Journal of the American Chemical Society
AU - MOLLOY, JOHN C.
AU - Seath, Ciaran P
AU - West, Matthew J
AU - Mclaughlin, Calum
AU - Fazakerley, Neal J
AU - Kennedy, M R
AU - Nelson, D J
AU - Watson, Allan J. B.
PY - 2017
DA - 2017/12/22
PB - American Chemical Society (ACS)
SP - 126-130
IS - 1
VL - 140
PMID - 29257859
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{2017_MOLLOY,
author = {JOHN C. MOLLOY and Ciaran P Seath and Matthew J West and Calum Mclaughlin and Neal J Fazakerley and M R Kennedy and D J Nelson and Allan J. B. Watson},
title = {Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch},
journal = {Journal of the American Chemical Society},
year = {2017},
volume = {140},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jacs.7b11180},
number = {1},
pages = {126--130},
doi = {10.1021/jacs.7b11180}
}
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MLA
Скопировать
MOLLOY, JOHN C., et al. “Interrogating Pd(II) Anion Metathesis Using a Bifunctional Chemical Probe: A Transmetalation Switch.” Journal of the American Chemical Society, vol. 140, no. 1, Dec. 2017, pp. 126-130. https://doi.org/10.1021/jacs.7b11180.