Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling
Publication type: Journal Article
Publication date: 2017-12-20
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
29202243
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
An asymmetric Ni-catalyzed reductive cross-coupling has been developed to prepare enantioenriched allylic silanes. This enantioselective reductive alkenylation proceeds under mild conditions and exhibits good functional group tolerance. The chiral allylic silanes prepared here undergo a variety of stereospecific transformations, including intramolecular Hosomi-Sakurai reactions, to set vicinal stereogenic centers with excellent transfer of chirality.
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194
Total citations:
194
Citations from 2024:
45
(23.19%)
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GOST
Copy
Hofstra J. L. et al. Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling // Journal of the American Chemical Society. 2017. Vol. 140. No. 1. pp. 139-142.
GOST all authors (up to 50)
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Hofstra J. L., Cherney A. H., Ordner C. M., Reisman S. E. Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling // Journal of the American Chemical Society. 2017. Vol. 140. No. 1. pp. 139-142.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.7b11707
UR - https://doi.org/10.1021/jacs.7b11707
TI - Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling
T2 - Journal of the American Chemical Society
AU - Hofstra, Julie L
AU - Cherney, Alan H
AU - Ordner, Ciara M
AU - Reisman, Sarah E
PY - 2017
DA - 2017/12/20
PB - American Chemical Society (ACS)
SP - 139-142
IS - 1
VL - 140
PMID - 29202243
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2017_Hofstra,
author = {Julie L Hofstra and Alan H Cherney and Ciara M Ordner and Sarah E Reisman},
title = {Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling},
journal = {Journal of the American Chemical Society},
year = {2017},
volume = {140},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jacs.7b11707},
number = {1},
pages = {139--142},
doi = {10.1021/jacs.7b11707}
}
Cite this
MLA
Copy
Hofstra, Julie L., et al. “Synthesis of Enantioenriched Allylic Silanes via Nickel-Catalyzed Reductive Cross-Coupling.” Journal of the American Chemical Society, vol. 140, no. 1, Dec. 2017, pp. 139-142. https://doi.org/10.1021/jacs.7b11707.