Journal of the American Chemical Society, volume 140, issue 5, pages 1612-1616
δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer
2
Jiuzhou Pharmaceutical, Zhejiang 318000, China
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Publication type: Journal Article
Publication date: 2018-01-30
Q1
Q1
SJR: 5.489
CiteScore: 24.4
Impact factor: 14.4
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
We demonstrate the application of ligand-to-metal charge transfer (LMCT) excitation to the direct catalytic generation of energetically challenging alkoxy radicals from alcohols through a coordination-LMCT-homolysis process with an abundant and inexpensive cerium salt as the catalyst. This catalytic manifold provides a simple and efficient way to utilize the characteristic reactivity and selectivity of transient alkoxy radicals for δ-selective C-H bond functionalization. Under mild redox-neutral conditions without the need for prefunctionalization, this method provides a versatile platform to access molecular complexity from simple and abundant alcohols.
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Hu A. et al. δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer // Journal of the American Chemical Society. 2018. Vol. 140. No. 5. pp. 1612-1616.
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Hu A., Guo J. J., Pan H., Tang H., Gao Z., Zuo Z. δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer // Journal of the American Chemical Society. 2018. Vol. 140. No. 5. pp. 1612-1616.
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TY - JOUR
DO - 10.1021/jacs.7b13131
UR - https://doi.org/10.1021/jacs.7b13131
TI - δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer
T2 - Journal of the American Chemical Society
AU - Hu, Anhua
AU - Guo, Jing Jing
AU - Pan, Hui
AU - Tang, Haoming
AU - Gao, Zhaobo
AU - Zuo, Zhiwei
PY - 2018
DA - 2018/01/30
PB - American Chemical Society (ACS)
SP - 1612-1616
IS - 5
VL - 140
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2018_Hu,
author = {Anhua Hu and Jing Jing Guo and Hui Pan and Haoming Tang and Zhaobo Gao and Zhiwei Zuo},
title = {δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer},
journal = {Journal of the American Chemical Society},
year = {2018},
volume = {140},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jacs.7b13131},
number = {5},
pages = {1612--1616},
doi = {10.1021/jacs.7b13131}
}
Cite this
MLA
Copy
Hu, Anhua, et al. “δ-Selective Functionalization of Alkanols Enabled by Visible-Light-Induced Ligand-to-Metal Charge Transfer.” Journal of the American Chemical Society, vol. 140, no. 5, Jan. 2018, pp. 1612-1616. https://doi.org/10.1021/jacs.7b13131.