Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N–N σ-Bonded Dimer
Publication type: Journal Article
Publication date: 2018-03-07
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
29513996
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Crystals of the heterocyclic radical naphtho-1,3,2-dithiazolyl NDTA display magnetic bistability with a well-defined hysteretic phase transition at Tc↓ = 128(2) K and Tc↑ = 188(2) K. The magnetic signature arises from a radical/dimer interconversion involving one of the two independent π-radicals in the P1̅ unit cell. Variable temperature X-ray crystallography has established that while all the radicals in HT-NDTA serve as paramagnetic ( S = 1/2) centers, half of the radicals in LT-NDTA form closed-shell N-N σ-bonded dimers ( S = 0) and half retain their S = 1/2 spin state. The wide window of bistability (60 K) may be attributed to the large structural changes that accompany the phase transition.
Found
Nothing found, try to update filter.
Found
Nothing found, try to update filter.
Top-30
Journals
|
1
2
3
4
5
6
7
|
|
|
Journal of the American Chemical Society
7 publications, 17.5%
|
|
|
Crystal Growth and Design
4 publications, 10%
|
|
|
Physical Chemistry Chemical Physics
4 publications, 10%
|
|
|
Mendeleev Communications
2 publications, 5%
|
|
|
Asian Journal of Organic Chemistry
1 publication, 2.5%
|
|
|
Chem
1 publication, 2.5%
|
|
|
Angewandte Chemie - International Edition
1 publication, 2.5%
|
|
|
Angewandte Chemie
1 publication, 2.5%
|
|
|
Advanced Materials
1 publication, 2.5%
|
|
|
ChemistrySelect
1 publication, 2.5%
|
|
|
Chinese Journal of Chemistry
1 publication, 2.5%
|
|
|
ACS Omega
1 publication, 2.5%
|
|
|
Journal of Physical Chemistry B
1 publication, 2.5%
|
|
|
Chemistry of Materials
1 publication, 2.5%
|
|
|
Journal of Materials Chemistry C
1 publication, 2.5%
|
|
|
CrystEngComm
1 publication, 2.5%
|
|
|
Chemical Science
1 publication, 2.5%
|
|
|
Journal of Physics and Chemistry of Solids
1 publication, 2.5%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 2.5%
|
|
|
Advances in Heterocyclic Chemistry
1 publication, 2.5%
|
|
|
Synlett
1 publication, 2.5%
|
|
|
ChemPlusChem
1 publication, 2.5%
|
|
|
Russian Chemical Reviews
1 publication, 2.5%
|
|
|
Journal of Physical Chemistry C
1 publication, 2.5%
|
|
|
Inorganic Chemistry Frontiers
1 publication, 2.5%
|
|
|
1
2
3
4
5
6
7
|
Publishers
|
2
4
6
8
10
12
14
16
|
|
|
American Chemical Society (ACS)
15 publications, 37.5%
|
|
|
Wiley
8 publications, 20%
|
|
|
Royal Society of Chemistry (RSC)
8 publications, 20%
|
|
|
Elsevier
4 publications, 10%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
2 publications, 5%
|
|
|
Georg Thieme Verlag KG
1 publication, 2.5%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 2.5%
|
|
|
2
4
6
8
10
12
14
16
|
- We do not take into account publications without a DOI.
- Statistics recalculated weekly.
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
40
Total citations:
40
Citations from 2024:
5
(12%)
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Bates D. et al. Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N–N σ-Bonded Dimer // Journal of the American Chemical Society. 2018. Vol. 140. No. 11. pp. 3846-3849.
GOST all authors (up to 50)
Copy
Bates D., Robertson C. A., Leitch A. A., Dube P., Oakley R. Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N–N σ-Bonded Dimer // Journal of the American Chemical Society. 2018. Vol. 140. No. 11. pp. 3846-3849.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacs.7b13699
UR - https://doi.org/10.1021/jacs.7b13699
TI - Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N–N σ-Bonded Dimer
T2 - Journal of the American Chemical Society
AU - Bates, Demetris
AU - Robertson, Craig A.
AU - Leitch, Alicea A.
AU - Dube, Paul
AU - Oakley, Richard
PY - 2018
DA - 2018/03/07
PB - American Chemical Society (ACS)
SP - 3846-3849
IS - 11
VL - 140
PMID - 29513996
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2018_Bates,
author = {Demetris Bates and Craig A. Robertson and Alicea A. Leitch and Paul Dube and Richard Oakley},
title = {Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N–N σ-Bonded Dimer},
journal = {Journal of the American Chemical Society},
year = {2018},
volume = {140},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/jacs.7b13699},
number = {11},
pages = {3846--3849},
doi = {10.1021/jacs.7b13699}
}
Cite this
MLA
Copy
Bates, Demetris, et al. “Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N–N σ-Bonded Dimer.” Journal of the American Chemical Society, vol. 140, no. 11, Mar. 2018, pp. 3846-3849. https://doi.org/10.1021/jacs.7b13699.