volume 140 issue 15 pages 5023-5027

Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols

Publication typeJournal Article
Publication date2018-03-30
scimago Q1
wos Q1
SJR5.554
CiteScore22.5
Impact factor15.6
ISSN00027863, 15205126
PubMed ID:  29601188
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The use of (L)Ni( o-tolyl)Cl precatalysts (L = PAd-DalPhos or CyPAd-DalPhos) enables the C( sp2)-O cross-coupling of primary, secondary, or tertiary aliphatic alcohols with (hetero)aryl electrophiles, including unprecedented examples of such nickel-catalyzed transformations employing (hetero)aryl chlorides, sulfonates, and pivalates. In addition to offering a competitive alternative to palladium catalysis, this work establishes the feasibility of utilizing ancillary ligation as a complementary means of promoting challenging nickel-catalyzed C( sp2)-O cross-couplings, without recourse to precious-metal photoredox catalytic methods.
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GOST Copy
Macqueen P. M. et al. Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols // Journal of the American Chemical Society. 2018. Vol. 140. No. 15. pp. 5023-5027.
GOST all authors (up to 50) Copy
Macqueen P. M., Tassone J. P., Diaz C., Stradiotto M. Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols // Journal of the American Chemical Society. 2018. Vol. 140. No. 15. pp. 5023-5027.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/jacs.8b01800
UR - https://doi.org/10.1021/jacs.8b01800
TI - Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols
T2 - Journal of the American Chemical Society
AU - Macqueen, Preston M
AU - Tassone, Joseph P
AU - Diaz, Carlos
AU - Stradiotto, M.
PY - 2018
DA - 2018/03/30
PB - American Chemical Society (ACS)
SP - 5023-5027
IS - 15
VL - 140
PMID - 29601188
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2018_Macqueen,
author = {Preston M Macqueen and Joseph P Tassone and Carlos Diaz and M. Stradiotto},
title = {Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols},
journal = {Journal of the American Chemical Society},
year = {2018},
volume = {140},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/jacs.8b01800},
number = {15},
pages = {5023--5027},
doi = {10.1021/jacs.8b01800}
}
MLA
Cite this
MLA Copy
Macqueen, Preston M., et al. “Exploiting Ancillary Ligation To Enable Nickel-Catalyzed C–O Cross-Couplings of Aryl Electrophiles with Aliphatic Alcohols.” Journal of the American Chemical Society, vol. 140, no. 15, Mar. 2018, pp. 5023-5027. https://doi.org/10.1021/jacs.8b01800.