In Operando Synchrotron Diffraction and in Operando X-ray Absorption Spectroscopy Investigations of Orthorhombic V2O5 Nanowires as Cathode Materials for Mg-Ion Batteries.
Qiang Fu
1
,
Angelina Sarapulova
1
,
Vanessa Trouillet
1, 2
,
Lihua Zhu
1
,
François Fauth
3
,
Stefan Mangold
4
,
Edmund Welter
5
,
Sylvio Indris
1, 6
,
Michael Knapp
1, 6
,
Sonia Dsoke
1, 6
,
Natalia Bramnik
1
,
H. Ehrenberg
1, 6
Publication type: Journal Article
Publication date: 2019-01-17
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
30652858
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Orthorhombic V2O5 nanowires were successfully synthesized via a hydrothermal method. A cell-configuration system was built utilizing V2O5 as the cathode and 1 M Mg(ClO4)2 electrolyte within acetonitrile, together with Mg xMo6S8 ( x ≈ 2) as the anode to investigate the structural evolution and oxidation state and local structural changes of V2O5. The V2O5 nanowires deliver an initial discharge/charge capacity of 103 mAh g-1/110 mAh g-1 and the highest discharge capacity of 130 mAh g-1 in the sixth cycle at C/20 rate in the cell-configuration system. In operando synchrotron diffraction and in operando X-ray absorption spectroscopy together with ex situ Raman and X-ray photoelectron spectroscopy reveal the reversibility of magnesium insertion/extraction and provide information on the crystal structure evolution and changes of the oxidation states during cycling.
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96
Total citations:
96
Citations from 2024:
34
(35.42%)
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GOST
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Fu Q. et al. In Operando Synchrotron Diffraction and in Operando X-ray Absorption Spectroscopy Investigations of Orthorhombic V2O5 Nanowires as Cathode Materials for Mg-Ion Batteries. // Journal of the American Chemical Society. 2019. Vol. 141. No. 6. pp. 2305-2315.
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Fu Q., Sarapulova A., Trouillet V., Zhu L., Fauth F., Mangold S., Welter E., Indris S., Knapp M., Dsoke S., Bramnik N., Ehrenberg H. In Operando Synchrotron Diffraction and in Operando X-ray Absorption Spectroscopy Investigations of Orthorhombic V2O5 Nanowires as Cathode Materials for Mg-Ion Batteries. // Journal of the American Chemical Society. 2019. Vol. 141. No. 6. pp. 2305-2315.
Cite this
RIS
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TY - JOUR
DO - 10.1021/jacs.8b08998
UR - https://doi.org/10.1021/jacs.8b08998
TI - In Operando Synchrotron Diffraction and in Operando X-ray Absorption Spectroscopy Investigations of Orthorhombic V2O5 Nanowires as Cathode Materials for Mg-Ion Batteries.
T2 - Journal of the American Chemical Society
AU - Fu, Qiang
AU - Sarapulova, Angelina
AU - Trouillet, Vanessa
AU - Zhu, Lihua
AU - Fauth, François
AU - Mangold, Stefan
AU - Welter, Edmund
AU - Indris, Sylvio
AU - Knapp, Michael
AU - Dsoke, Sonia
AU - Bramnik, Natalia
AU - Ehrenberg, H.
PY - 2019
DA - 2019/01/17
PB - American Chemical Society (ACS)
SP - 2305-2315
IS - 6
VL - 141
PMID - 30652858
SN - 0002-7863
SN - 1520-5126
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2019_Fu,
author = {Qiang Fu and Angelina Sarapulova and Vanessa Trouillet and Lihua Zhu and François Fauth and Stefan Mangold and Edmund Welter and Sylvio Indris and Michael Knapp and Sonia Dsoke and Natalia Bramnik and H. Ehrenberg},
title = {In Operando Synchrotron Diffraction and in Operando X-ray Absorption Spectroscopy Investigations of Orthorhombic V2O5 Nanowires as Cathode Materials for Mg-Ion Batteries.},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jacs.8b08998},
number = {6},
pages = {2305--2315},
doi = {10.1021/jacs.8b08998}
}
Cite this
MLA
Copy
Fu, Qiang, et al. “In Operando Synchrotron Diffraction and in Operando X-ray Absorption Spectroscopy Investigations of Orthorhombic V2O5 Nanowires as Cathode Materials for Mg-Ion Batteries..” Journal of the American Chemical Society, vol. 141, no. 6, Jan. 2019, pp. 2305-2315. https://doi.org/10.1021/jacs.8b08998.
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