Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts
Ershuai Liu
1
,
Jingkun Li
1
,
Li Jiao
2
,
Huong Thi Thanh Doan
1
,
Zeyan Liu
3
,
Zipeng Zhao
3
,
Yu Huang
3, 4
,
K. M. Abraham
1
,
Sanjeev Mukerjee
1
,
Qingying Jia
1
Publication type: Journal Article
Publication date: 2019-01-23
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
30673227
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Despite the fundamental and practical significance of the hydrogen evolution and oxidation reactions (HER/HOR), their kinetics in base remain unclear. Herein, we show that the alkaline HER/HOR kinetics can be unified by the catalytic roles of the adsorbed hydroxyl (OHad)-water-alkali metal cation (AM+) adducts, on the basis of the observations that enriching the OHad abundance via surface Ni benefits the HER/HOR; increasing the AM+ concentration only promotes the HER, while varying the identity of AM+ affects both HER/HOR. The presence of OHad-(H2O) x-AM+ in the double-layer region facilitates the OHad removal into the bulk, forming OH--(H2O) x-AM+ as per the hard-soft acid-base theory, thereby selectively promoting the HER. It can be detrimental to the HOR as per the bifunctional mechanism, as the AM+ destabilizes the OHad, which is further supported by the CO oxidation results. This new notion may be important for alkaline electrochemistry.
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320
Total citations:
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Citations from 2025:
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(20.63%)
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Liu E. et al. Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts // Journal of the American Chemical Society. 2019. Vol. 141. No. 7. pp. 3232-3239.
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Liu E., Li J., Jiao L., Doan H. T. T., Liu Z., Zhao Z., Huang Yu., Abraham K. M., Mukerjee S., Jia Q. Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts // Journal of the American Chemical Society. 2019. Vol. 141. No. 7. pp. 3232-3239.
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TY - JOUR
DO - 10.1021/jacs.8b13228
UR - https://doi.org/10.1021/jacs.8b13228
TI - Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts
T2 - Journal of the American Chemical Society
AU - Liu, Ershuai
AU - Li, Jingkun
AU - Jiao, Li
AU - Doan, Huong Thi Thanh
AU - Liu, Zeyan
AU - Zhao, Zipeng
AU - Huang, Yu
AU - Abraham, K. M.
AU - Mukerjee, Sanjeev
AU - Jia, Qingying
PY - 2019
DA - 2019/01/23
PB - American Chemical Society (ACS)
SP - 3232-3239
IS - 7
VL - 141
PMID - 30673227
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2019_Liu,
author = {Ershuai Liu and Jingkun Li and Li Jiao and Huong Thi Thanh Doan and Zeyan Liu and Zipeng Zhao and Yu Huang and K. M. Abraham and Sanjeev Mukerjee and Qingying Jia},
title = {Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/jacs.8b13228},
number = {7},
pages = {3232--3239},
doi = {10.1021/jacs.8b13228}
}
Cite this
MLA
Copy
Liu, Ershuai, et al. “Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts.” Journal of the American Chemical Society, vol. 141, no. 7, Jan. 2019, pp. 3232-3239. https://doi.org/10.1021/jacs.8b13228.