Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4
Yulong Sun
1
,
Yue Chao Wang
2
,
Xiuli Zhang
3
,
Yuanhua Xia
4
,
Linfeng Peng
1
,
Huanhuan Jia
1
,
Hanxiao Li
2
,
Liangfei Bai
4
,
Jiwen Feng
3
,
Hong Jiang
2
,
Jia Xie
1
2
4
Key Laboratory
of Neutron Physics and Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang, Sichuan 621999, China
|
Publication type: Journal Article
Publication date: 2019-03-26
scimago Q1
wos Q1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
30912936
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Sodium superionic conductors are keys to develop high safety and low cost all-solid-state sodium batteries. Among developed sodium ionic conductors, antiperovskite-type ionic conductors have attracted vast interest due to their high structural tolerance and good formability. Herein, we successfully synthesize Na3OBH4 with cubic antiperovskite structure by solid-state reaction from Na2O and NaBH4. Na3OBH4 exhibits ionic conductivity of 4.4 × 10-3 S cm-1 at room temperature (1.1 × 10-2 S cm-1 at 328 K) and activation energy of 0.25 eV. The ionic conductivity is 4 orders of magnitude higher than the existing antiperovskite Na3OX (X = Cl, Br, I). It is shown that such enhancement is not only due to the specific cubic antiperovskite structure of Na3OBH4 but also because of the rotation of BH4 cluster anion. This work deepens the understanding of the antiperovskite structure and the role of cluster anions for superionic conduction.
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154
Total citations:
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Citations from 2024:
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Sun Y. et al. Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4 // Journal of the American Chemical Society. 2019. Vol. 141. No. 14. pp. 5640-5644.
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Sun Y., Wang Y. C., Zhang X., Xia Y., Peng L., Jia H., Li H., Bai L., Feng J., Jiang H., Xie J. Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4 // Journal of the American Chemical Society. 2019. Vol. 141. No. 14. pp. 5640-5644.
Cite this
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TY - JOUR
DO - 10.1021/jacs.9b01746
UR - https://doi.org/10.1021/jacs.9b01746
TI - Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4
T2 - Journal of the American Chemical Society
AU - Sun, Yulong
AU - Wang, Yue Chao
AU - Zhang, Xiuli
AU - Xia, Yuanhua
AU - Peng, Linfeng
AU - Jia, Huanhuan
AU - Li, Hanxiao
AU - Bai, Liangfei
AU - Feng, Jiwen
AU - Jiang, Hong
AU - Xie, Jia
PY - 2019
DA - 2019/03/26
PB - American Chemical Society (ACS)
SP - 5640-5644
IS - 14
VL - 141
PMID - 30912936
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (up to 50 authors)
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@article{2019_Sun,
author = {Yulong Sun and Yue Chao Wang and Xiuli Zhang and Yuanhua Xia and Linfeng Peng and Huanhuan Jia and Hanxiao Li and Liangfei Bai and Jiwen Feng and Hong Jiang and Jia Xie},
title = {Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/jacs.9b01746},
number = {14},
pages = {5640--5644},
doi = {10.1021/jacs.9b01746}
}
Cite this
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Sun, Yulong, et al. “Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4.” Journal of the American Chemical Society, vol. 141, no. 14, Mar. 2019, pp. 5640-5644. https://doi.org/10.1021/jacs.9b01746.
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