Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4
Тип публикации: Journal Article
Дата публикации: 2019-03-26
scimago Q1
wos Q1
БС1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
30912936
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
Sodium superionic conductors are keys to develop high safety and low cost all-solid-state sodium batteries. Among developed sodium ionic conductors, antiperovskite-type ionic conductors have attracted vast interest due to their high structural tolerance and good formability. Herein, we successfully synthesize Na3OBH4 with cubic antiperovskite structure by solid-state reaction from Na2O and NaBH4. Na3OBH4 exhibits ionic conductivity of 4.4 × 10-3 S cm-1 at room temperature (1.1 × 10-2 S cm-1 at 328 K) and activation energy of 0.25 eV. The ionic conductivity is 4 orders of magnitude higher than the existing antiperovskite Na3OX (X = Cl, Br, I). It is shown that such enhancement is not only due to the specific cubic antiperovskite structure of Na3OBH4 but also because of the rotation of BH4 cluster anion. This work deepens the understanding of the antiperovskite structure and the role of cluster anions for superionic conduction.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Топ-30
Журналы
|
2
4
6
8
10
12
14
|
|
|
Journal of Materials Chemistry A
14 публикаций, 8.86%
|
|
|
Chemistry of Materials
11 публикаций, 6.96%
|
|
|
Energy Storage Materials
8 публикаций, 5.06%
|
|
|
Journal of Physical Chemistry C
7 публикаций, 4.43%
|
|
|
ACS applied materials & interfaces
6 публикаций, 3.8%
|
|
|
Physical Chemistry Chemical Physics
6 публикаций, 3.8%
|
|
|
Journal of Physical Chemistry Letters
5 публикаций, 3.16%
|
|
|
Journal of the American Chemical Society
4 публикации, 2.53%
|
|
|
Advanced Functional Materials
4 публикации, 2.53%
|
|
|
Journal of Power Sources
4 публикации, 2.53%
|
|
|
ACS Applied Energy Materials
4 публикации, 2.53%
|
|
|
Electrochemical Energy Reviews
4 публикации, 2.53%
|
|
|
Journal of Energy Storage
4 публикации, 2.53%
|
|
|
Chemical Reviews
3 публикации, 1.9%
|
|
|
Inorganic Chemistry
3 публикации, 1.9%
|
|
|
Nature Communications
3 публикации, 1.9%
|
|
|
InfoMat
3 публикации, 1.9%
|
|
|
Materials Horizons
3 публикации, 1.9%
|
|
|
Advanced Energy Materials
3 публикации, 1.9%
|
|
|
Angewandte Chemie
3 публикации, 1.9%
|
|
|
Angewandte Chemie - International Edition
3 публикации, 1.9%
|
|
|
Nature Reviews Materials
2 публикации, 1.27%
|
|
|
ACS Materials Au
2 публикации, 1.27%
|
|
|
Chemical Society Reviews
2 публикации, 1.27%
|
|
|
Coordination Chemistry Reviews
2 публикации, 1.27%
|
|
|
Chinese Chemical Letters
2 публикации, 1.27%
|
|
|
Nano Energy
2 публикации, 1.27%
|
|
|
Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences
1 публикация, 0.63%
|
|
|
Batteries
1 публикация, 0.63%
|
|
|
Jiegou Huaxue
1 публикация, 0.63%
|
|
|
2
4
6
8
10
12
14
|
Издатели
|
5
10
15
20
25
30
35
40
45
50
|
|
|
American Chemical Society (ACS)
49 публикаций, 31.01%
|
|
|
Elsevier
36 публикаций, 22.78%
|
|
|
Royal Society of Chemistry (RSC)
26 публикаций, 16.46%
|
|
|
Wiley
22 публикации, 13.92%
|
|
|
Springer Nature
12 публикаций, 7.59%
|
|
|
American Physical Society (APS)
3 публикации, 1.9%
|
|
|
AIP Publishing
2 публикации, 1.27%
|
|
|
The Royal Society
1 публикация, 0.63%
|
|
|
MDPI
1 публикация, 0.63%
|
|
|
Chinese Academy of Sciences
1 публикация, 0.63%
|
|
|
Japan Society of Applied Physics
1 публикация, 0.63%
|
|
|
Oxford University Press
1 публикация, 0.63%
|
|
|
Acta Physica Sinica, Chinese Physical Society and Institute of Physics, Chinese Academy of Sciences
1 публикация, 0.63%
|
|
|
Annual Reviews
1 публикация, 0.63%
|
|
|
Proceedings of the National Academy of Sciences (PNAS)
1 публикация, 0.63%
|
|
|
5
10
15
20
25
30
35
40
45
50
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
158
Всего цитирований:
158
Цитирований c 2025:
36
(22.78%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Sun Y. et al. Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4 // Journal of the American Chemical Society. 2019. Vol. 141. No. 14. pp. 5640-5644.
ГОСТ со всеми авторами (до 50)
Скопировать
Sun Y., Wang Y. C., Zhang X., Xia Y., Peng L., Jia H., Li H., Bai L., Feng J., Jiang H., Xie J. Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4 // Journal of the American Chemical Society. 2019. Vol. 141. No. 14. pp. 5640-5644.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/jacs.9b01746
UR - https://doi.org/10.1021/jacs.9b01746
TI - Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4
T2 - Journal of the American Chemical Society
AU - Sun, Yulong
AU - Wang, Yue Chao
AU - Zhang, Xiuli
AU - Xia, Yuanhua
AU - Peng, Linfeng
AU - Jia, Huanhuan
AU - Li, Hanxiao
AU - Bai, Liangfei
AU - Feng, Jiwen
AU - Jiang, Hong
AU - Xie, Jia
PY - 2019
DA - 2019/03/26
PB - American Chemical Society (ACS)
SP - 5640-5644
IS - 14
VL - 141
PMID - 30912936
SN - 0002-7863
SN - 1520-5126
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2019_Sun,
author = {Yulong Sun and Yue Chao Wang and Xiuli Zhang and Yuanhua Xia and Linfeng Peng and Huanhuan Jia and Hanxiao Li and Liangfei Bai and Jiwen Feng and Hong Jiang and Jia Xie},
title = {Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/jacs.9b01746},
number = {14},
pages = {5640--5644},
doi = {10.1021/jacs.9b01746}
}
Цитировать
MLA
Скопировать
Sun, Yulong, et al. “Rotational Cluster Anion Enabling Superionic Conductivity in Sodium-Rich Antiperovskite Na3OBH4.” Journal of the American Chemical Society, vol. 141, no. 14, Mar. 2019, pp. 5640-5644. https://doi.org/10.1021/jacs.9b01746.