Annihilation Versus Excimer Formation by the Triplet Pair in Triplet–Triplet Annihilation Photon Upconversion
Тип публикации: Journal Article
Дата публикации: 2019-05-25
scimago Q1
wos Q1
БС1
SJR: 5.554
CiteScore: 22.5
Impact factor: 15.6
ISSN: 00027863, 15205126
PubMed ID:
31131601
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Краткое описание
The triplet pair is the key functional unit in triplet-triplet annihilation photon upconversion. The same molecular properties that stabilize the triplet pair also allow dimers to form on the singlet energy surface, creating an unwanted energy relaxation pathway. Here we show that excimer formation most likely is a consequence of a triplet dimer formed before the annihilation event. Polarity-dependent studies were performed to elucidate how to promote wanted emission pathways over excimer formation. Furthermore, we show that the yield of triplet-triplet annihilation is increased in higher-viscosity solvents. The results will bring new insights in how to increase the upconversion efficiency and how to avoid energy-loss channels.
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ГОСТ
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Ye C. et al. Annihilation Versus Excimer Formation by the Triplet Pair in Triplet–Triplet Annihilation Photon Upconversion // Journal of the American Chemical Society. 2019. Vol. 141. No. 24. pp. 9578-9584.
ГОСТ со всеми авторами (до 50)
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Ye C., Gray V., Mårtensson J., Börjesson K. Annihilation Versus Excimer Formation by the Triplet Pair in Triplet–Triplet Annihilation Photon Upconversion // Journal of the American Chemical Society. 2019. Vol. 141. No. 24. pp. 9578-9584.
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RIS
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TY - JOUR
DO - 10.1021/jacs.9b02302
UR - https://doi.org/10.1021/jacs.9b02302
TI - Annihilation Versus Excimer Formation by the Triplet Pair in Triplet–Triplet Annihilation Photon Upconversion
T2 - Journal of the American Chemical Society
AU - Ye, Chen
AU - Gray, Victor
AU - Mårtensson, Jerker
AU - Börjesson, Karl
PY - 2019
DA - 2019/05/25
PB - American Chemical Society (ACS)
SP - 9578-9584
IS - 24
VL - 141
PMID - 31131601
SN - 0002-7863
SN - 1520-5126
ER -
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BibTex (до 50 авторов)
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@article{2019_Ye,
author = {Chen Ye and Victor Gray and Jerker Mårtensson and Karl Börjesson},
title = {Annihilation Versus Excimer Formation by the Triplet Pair in Triplet–Triplet Annihilation Photon Upconversion},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/jacs.9b02302},
number = {24},
pages = {9578--9584},
doi = {10.1021/jacs.9b02302}
}
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MLA
Скопировать
Ye, Chen, et al. “Annihilation Versus Excimer Formation by the Triplet Pair in Triplet–Triplet Annihilation Photon Upconversion.” Journal of the American Chemical Society, vol. 141, no. 24, May. 2019, pp. 9578-9584. https://doi.org/10.1021/jacs.9b02302.