Journal of the American Chemical Society, volume 141, issue 23, pages 9165-9169
Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries
Jia-Yan Liang
1, 2
,
Xian Xiang Zeng
3
,
Xudong Zhang
1
,
T.T. Zuo
1, 2
,
Min Yan
1
,
Yaxia Yin
1, 2
,
Ji Lei Shi
1
,
Xiong‐Wei Wu
3
,
Yuguo Guo
1, 2
,
Lijun Wan
1, 2
Publication type: Journal Article
Publication date: 2019-05-29
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The fast-ionic-conducting ceramic electrolyte is promising for next-generation high-energy-density Li-metal batteries, yet its application suffers from the high interfacial resistance and poor interfacial stability. In this study, the compatible solid-state electrolyte was designed by coating Li1.4Al0.4Ti1.6(PO4)3 (LATP) with polyacrylonitrile (PAN) and polyethylene oxide (PEO) oppositely to satisfy deliberately the disparate interface demands. Wherein, the upper PAN constructs soft-contact with LiNi0.6Mn0.2Co0.2O2, and the lower PEO protects LATP from being reduced, guaranteeing high-voltage tolerance and improved stability toward Li-metal anode performed in one ceramic. Moreover, the core function of LATP is amplified to guide homogeneous ions distribution and hence suppresses the formation of a space-charge layer across interfaces, uncovered by the COMSOL Multiphysics concentration field simulation. Thus, such a bifunctional modified ceramic electrolyte integrates the respective superiority to render Li-metal batteries with excellent cycling stability (89% after 120 cycles), high Coulombic efficiency (exceeding 99.5% per cycle), and a dendrite-free Li anode at 60 °C, which represents an overall design of ceramic interface engineering for future practical solid battery systems.
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Citations by publishers
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Elsevier
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Liang J. et al. Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries // Journal of the American Chemical Society. 2019. Vol. 141. No. 23. pp. 9165-9169.
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Liang J., Zeng X. X., Zhang X., Zuo T., Yan M., Yin Y., Shi J. L., Wu X., Guo Y., Wan L. Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries // Journal of the American Chemical Society. 2019. Vol. 141. No. 23. pp. 9165-9169.
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TY - JOUR
DO - 10.1021/jacs.9b03517
UR - https://doi.org/10.1021/jacs.9b03517
TI - Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries
T2 - Journal of the American Chemical Society
AU - Liang, Jia-Yan
AU - Yan, Min
AU - Zeng, Xian Xiang
AU - Zuo, T.T.
AU - Yin, Yaxia
AU - Shi, Ji Lei
AU - Wu, Xiong‐Wei
AU - Guo, Yuguo
AU - Wan, Lijun
AU - Zhang, Xudong
PY - 2019
DA - 2019/05/29 00:00:00
PB - American Chemical Society (ACS)
SP - 9165-9169
IS - 23
VL - 141
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2019_Liang,
author = {Jia-Yan Liang and Min Yan and Xian Xiang Zeng and T.T. Zuo and Yaxia Yin and Ji Lei Shi and Xiong‐Wei Wu and Yuguo Guo and Lijun Wan and Xudong Zhang},
title = {Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/jacs.9b03517},
number = {23},
pages = {9165--9169},
doi = {10.1021/jacs.9b03517}
}
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MLA
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Liang, Jia-Yan, et al. “Engineering Janus Interfaces of Ceramic Electrolyte via Distinct Functional Polymers for Stable High-Voltage Li-Metal Batteries.” Journal of the American Chemical Society, vol. 141, no. 23, May. 2019, pp. 9165-9169. https://doi.org/10.1021/jacs.9b03517.