Journal of the American Chemical Society, volume 141, issue 23, pages 9422-9429

Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes

Publication typeJournal Article
Publication date2019-05-22
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor15
ISSN00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The stability of a battery is strongly dependent on the feature of solid electrolyte interphase (SEI). The electrical double layer forms prior to the formation of SEI at the interface between the Li metal anode and the electrolyte. The fundamental understanding on the regulation of the SEI structure and stability on Li surface through the structure of the electrical double layer is highly necessary for safe batteries. Herein, the interfacial chemistry of the SEI is correlated with the initial Li surface adsorption electrical double layer at the nanoscale through theoretical and experimental analysis. Under the premise of the constant solvation sheath structure of Li+ in bulk electrolyte, a trace amount of lithium nitrate (LiNO3) and copper fluoride (CuF2) were employed in electrolytes to build robust electric double layer structures on a Li metal surface. The distinct results were achieved with the initial competitive adsorption of bis(fluorosulfonyl)imide ion (FSI-), fluoride ion (F-), and nitrate ion (NO3-) in the inner Helmholtz plane. As a result, Cu-NO3- complexes are preferentially adsorbed and reduced to form the SEI. The modified Li metal electrode can achieve an average Coulombic efficiency of 99.5% over 500 cycles, enabling a long lifespan and high capacity retention of practical rechargeable batteries. The as-proposed mechanism bridges the gap between Li+ solvation and the adsorption about the electrode interface formation in a working battery.

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GOST |
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GOST Copy
YAN C. et al. Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes // Journal of the American Chemical Society. 2019. Vol. 141. No. 23. pp. 9422-9429.
GOST all authors (up to 50) Copy
YAN C., Li H. R., Chen X., Zhang X., Cheng X., Xu R., Huang J., Zhang Q. Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes // Journal of the American Chemical Society. 2019. Vol. 141. No. 23. pp. 9422-9429.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/jacs.9b05029
UR - https://doi.org/10.1021/jacs.9b05029
TI - Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes
T2 - Journal of the American Chemical Society
AU - YAN, CHONG
AU - Chen, Xiang
AU - Zhang, Xueqiang
AU - Cheng, Xin-Bing
AU - Huang, Jia-Qi
AU - Zhang, Qiang
AU - Li, Hao Ran
AU - Xu, Rui
PY - 2019
DA - 2019/05/22 00:00:00
PB - American Chemical Society (ACS)
SP - 9422-9429
IS - 23
VL - 141
SN - 0002-7863
SN - 1520-5126
ER -
BibTex |
Cite this
BibTex Copy
@article{2019_YAN,
author = {CHONG YAN and Xiang Chen and Xueqiang Zhang and Xin-Bing Cheng and Jia-Qi Huang and Qiang Zhang and Hao Ran Li and Rui Xu},
title = {Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/jacs.9b05029},
number = {23},
pages = {9422--9429},
doi = {10.1021/jacs.9b05029}
}
MLA
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MLA Copy
YAN, CHONG, et al. “Regulating the Inner Helmholtz Plane for Stable Solid Electrolyte Interphase on Lithium Metal Anodes.” Journal of the American Chemical Society, vol. 141, no. 23, May. 2019, pp. 9422-9429. https://doi.org/10.1021/jacs.9b05029.
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