Open Access
Bifurcated Halogen Bonding Involving Two Rhodium(I) Centers as an Integrated σ-Hole Acceptor
Publication type: Journal Article
Publication date: 2021-02-19
scimago Q1
wos Q1
SJR: 2.944
CiteScore: 12.4
Impact factor: 8.7
ISSN: 26913704
PubMed ID:
34467299
General Medicine
Abstract
The complexes [RhX(COD)]2 (X = Cl, Br; COD = 1,5-cyclooctadiene) form cocrystals with σ-hole iodine donors. X-ray diffraction studies and extensive theoretical considerations indicate that the d z2-orbitals of two positively charged rhodium(I) centers provide sufficient nucleophilicity to form a three-center halogen bond (XB) with the σ-hole donors. The two metal centers function as an integrated XB acceptor, providing assembly via a metal-involving XB.
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Metrics
57
Total citations:
57
Citations from 2024:
22
(38%)
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MLA
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GOST
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Eliseeva A. A. et al. Bifurcated Halogen Bonding Involving Two Rhodium(I) Centers as an Integrated σ-Hole Acceptor // JACS Au. 2021. Vol. 1. No. 3. pp. 354-361.
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Eliseeva A. A., Ivanov D. M., Rozhkov A. A., Ananyev I. V., Frontera A., Kukushkin V. Y. Bifurcated Halogen Bonding Involving Two Rhodium(I) Centers as an Integrated σ-Hole Acceptor // JACS Au. 2021. Vol. 1. No. 3. pp. 354-361.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jacsau.1c00012
UR - https://doi.org/10.1021/jacsau.1c00012
TI - Bifurcated Halogen Bonding Involving Two Rhodium(I) Centers as an Integrated σ-Hole Acceptor
T2 - JACS Au
AU - Eliseeva, Anastasiya A
AU - Ivanov, Daniil M
AU - Rozhkov, Anton Alekseevich
AU - Ananyev, Ivan V
AU - Frontera, Antonio
AU - Kukushkin, Vadim Yu.
PY - 2021
DA - 2021/02/19
PB - American Chemical Society (ACS)
SP - 354-361
IS - 3
VL - 1
PMID - 34467299
SN - 2691-3704
ER -
Cite this
BibTex (up to 50 authors)
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@article{2021_Eliseeva,
author = {Anastasiya A Eliseeva and Daniil M Ivanov and Anton Alekseevich Rozhkov and Ivan V Ananyev and Antonio Frontera and Vadim Yu. Kukushkin},
title = {Bifurcated Halogen Bonding Involving Two Rhodium(I) Centers as an Integrated σ-Hole Acceptor},
journal = {JACS Au},
year = {2021},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/jacsau.1c00012},
number = {3},
pages = {354--361},
doi = {10.1021/jacsau.1c00012}
}
Cite this
MLA
Copy
Eliseeva, Anastasiya A., et al. “Bifurcated Halogen Bonding Involving Two Rhodium(I) Centers as an Integrated σ-Hole Acceptor.” JACS Au, vol. 1, no. 3, Feb. 2021, pp. 354-361. https://doi.org/10.1021/jacsau.1c00012.