Model for Calculating the Density of Aqueous Electrolyte Solutions
1
SNC-Lavalin Inc., 455 René-Lévesque Boulevard West, Montréal QC, Canada H2Z 1Z3
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Publication type: Journal Article
Publication date: 2004-07-20
scimago Q2
wos Q2
SJR: 0.449
CiteScore: 4.0
Impact factor: 2.1
ISSN: 00219568, 15205134
General Chemistry
General Chemical Engineering
Abstract
A new model for calculating the density of aqueous solutions of electrolytes has been developed. Parameters for 59 electrolytes were established on the basis of an extensive critical review of the published literature for solutions of one electrolyte in water, with over 10 700 points included. The average difference between the calculated and experimental density of solutions of water and one electrolyte is 0.10 kg m-3 with a standard deviation of 1.44 kg m-3. The model was validated by predicting the density of systems of two or more electrolytes in water. The average difference between experimental and calculated values for over 1600 points is 0.003 kg m-3 with a standard deviation of 1.39 kg m-3. The electrolytes studied are AlCl3, Al2(SO4)3, BaCl2, CaCl2, CdCl2, CdSO4, CoCl2, CoSO4, CrCl3, Cr2(SO4)3, CuCl2, CuSO4, FeCl2, FeSO4, FeCl3, Fe2(SO4)3, HCl, HCN, HNO3, H3PO4, H2SO4, KCl, K2CO3, KNO3, KOH, K2SO4, LiCl, Li2SO4, MgCl2, MgSO4, MnCl2, MnSO4, NaBr, NaCl, NaClO3, Na2CO3, NaF, NaHCO3, NaH2PO4, Na2HPO...
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179
Total citations:
179
Citations from 2024:
40
(22.34%)
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GOST
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Laliberté M., Cooper W. E. Model for Calculating the Density of Aqueous Electrolyte Solutions // Journal of Chemical & Engineering Data. 2004. Vol. 49. No. 5. pp. 1141-1151.
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Laliberté M., Cooper W. E. Model for Calculating the Density of Aqueous Electrolyte Solutions // Journal of Chemical & Engineering Data. 2004. Vol. 49. No. 5. pp. 1141-1151.
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RIS
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TY - JOUR
DO - 10.1021/je0498659
UR - https://doi.org/10.1021/je0498659
TI - Model for Calculating the Density of Aqueous Electrolyte Solutions
T2 - Journal of Chemical & Engineering Data
AU - Laliberté, Marc
AU - Cooper, W Edward
PY - 2004
DA - 2004/07/20
PB - American Chemical Society (ACS)
SP - 1141-1151
IS - 5
VL - 49
SN - 0021-9568
SN - 1520-5134
ER -
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BibTex (up to 50 authors)
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@article{2004_Laliberté,
author = {Marc Laliberté and W Edward Cooper},
title = {Model for Calculating the Density of Aqueous Electrolyte Solutions},
journal = {Journal of Chemical & Engineering Data},
year = {2004},
volume = {49},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/je0498659},
number = {5},
pages = {1141--1151},
doi = {10.1021/je0498659}
}
Cite this
MLA
Copy
Laliberté, Marc, and W Edward Cooper. “Model for Calculating the Density of Aqueous Electrolyte Solutions.” Journal of Chemical & Engineering Data, vol. 49, no. 5, Jul. 2004, pp. 1141-1151. https://doi.org/10.1021/je0498659.