Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes)
Тип публикации: Journal Article
Дата публикации: 1993-02-01
scimago Q2
wos Q1
БС1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
Organic Chemistry
Краткое описание
The full details of a facile synthesis of structurally homogeneouspoly(3-alkylthiophene) (PAT's) is presented. In three steps from 3-bromothiophene, PAT's can be made with complete regiochemical control. We define structurally homogenous an a regiochemically well-defined polymer structure that in oar cane contains almsost exclusively head-to-tail couplings (HT-HT) (2,5-couplings between adjacent thiophene rings). By analysis of the NMR data, oar poly(n-butylthiophene) (5a) contains 93% HT-HT couplings, 98% of the desired regiochemistry is found in poly(n-hexylthiophene) (5b), 97% in poly(n-octylthiophene), (5c), and 95% in poly(n-dodecylthiophene), (5d)
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ГОСТ
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McCullough R. D. et al. Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes) // Journal of Organic Chemistry. 1993. Vol. 58. No. 4. pp. 904-912.
ГОСТ со всеми авторами (до 50)
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McCullough R. D., Lowe R. D., Jayaraman M., Anderson D. L. Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes) // Journal of Organic Chemistry. 1993. Vol. 58. No. 4. pp. 904-912.
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RIS
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TY - JOUR
DO - 10.1021/jo00056a024
UR - https://doi.org/10.1021/jo00056a024
TI - Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes)
T2 - Journal of Organic Chemistry
AU - McCullough, Richard D.
AU - Lowe, Renae D
AU - Jayaraman, Manikandan
AU - Anderson, Deborah L
PY - 1993
DA - 1993/02/01
PB - American Chemical Society (ACS)
SP - 904-912
IS - 4
VL - 58
SN - 0022-3263
SN - 1520-6904
ER -
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BibTex (до 50 авторов)
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@article{1993_McCullough,
author = {Richard D. McCullough and Renae D Lowe and Manikandan Jayaraman and Deborah L Anderson},
title = {Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes)},
journal = {Journal of Organic Chemistry},
year = {1993},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/jo00056a024},
number = {4},
pages = {904--912},
doi = {10.1021/jo00056a024}
}
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MLA
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McCullough, Richard D., et al. “Design, synthesis, and control of conducting polymer architectures: structurally homogeneous poly(3-alkylthiophenes).” Journal of Organic Chemistry, vol. 58, no. 4, Feb. 1993, pp. 904-912. https://doi.org/10.1021/jo00056a024.