Theoretical Study of Intramolecular Aldol Condensation of 1,6-Diketones: Trimethylsilyl Substituent Effect
Тип публикации: Journal Article
Дата публикации: 2000-08-11
scimago Q2
wos Q1
БС1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
10970329
Organic Chemistry
Краткое описание
Diastereoselective intramolecular aldol condensations are investigated in an experimental and computational study of 1, 6-diketones. Ab initio results show the importance of the acid medium and disapprove the possibility of a spontaneous cyclization, even for silylated compounds. The combination of both experimental and computational approaches brings valuable information on the mechanism and on the selectivity of the aldol reaction. It is found that the enolization of the diketone is a key step in acid-catalyzed mechanism. The cyclization step bears a very small activation energy. The dehydration of the aldols are discussed.
Найдено
Ничего не найдено, попробуйте изменить настройки фильтра.
Для доступа к списку цитирований публикации необходимо авторизоваться.
Топ-30
Журналы
|
1
2
|
|
|
Journal of the American Chemical Society
2 публикации, 8.7%
|
|
|
Tetrahedron Asymmetry
1 публикация, 4.35%
|
|
|
Tetrahedron Letters
1 публикация, 4.35%
|
|
|
Mendeleev Communications
1 публикация, 4.35%
|
|
|
Tetrahedron
1 публикация, 4.35%
|
|
|
ChemInform
1 публикация, 4.35%
|
|
|
ChemSusChem
1 публикация, 4.35%
|
|
|
European Journal of Organic Chemistry
1 публикация, 4.35%
|
|
|
Organic Letters
1 публикация, 4.35%
|
|
|
Journal of Organic Chemistry
1 публикация, 4.35%
|
|
|
ACS Catalysis
1 публикация, 4.35%
|
|
|
Doklady Chemistry
1 публикация, 4.35%
|
|
|
RSC Advances
1 публикация, 4.35%
|
|
|
Organic Chemistry Frontiers
1 публикация, 4.35%
|
|
|
Organic and Biomolecular Chemistry
1 публикация, 4.35%
|
|
|
Russian Journal of Physical Chemistry B
1 публикация, 4.35%
|
|
|
Phosphorus, Sulfur and Silicon and the Related Elements
1 публикация, 4.35%
|
|
|
Heterocycles
1 публикация, 4.35%
|
|
|
Synlett
1 публикация, 4.35%
|
|
|
Chemical Communications
1 публикация, 4.35%
|
|
|
Renewable and Sustainable Energy Reviews
1 публикация, 4.35%
|
|
|
1
2
|
Издатели
|
1
2
3
4
5
|
|
|
Elsevier
5 публикаций, 21.74%
|
|
|
American Chemical Society (ACS)
5 публикаций, 21.74%
|
|
|
Royal Society of Chemistry (RSC)
4 публикации, 17.39%
|
|
|
Wiley
3 публикации, 13.04%
|
|
|
Pleiades Publishing
2 публикации, 8.7%
|
|
|
OOO Zhurnal "Mendeleevskie Soobshcheniya"
1 публикация, 4.35%
|
|
|
Taylor & Francis
1 публикация, 4.35%
|
|
|
The Japan Institute of Heterocyclic Chemistry
1 публикация, 4.35%
|
|
|
Georg Thieme Verlag KG
1 публикация, 4.35%
|
|
|
1
2
3
4
5
|
- Мы не учитываем публикации, у которых нет DOI.
- Статистика публикаций обновляется еженедельно.
Вы ученый?
Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
23
Всего цитирований:
23
Цитирований c 2025:
2
(8.7%)
Цитировать
ГОСТ |
RIS |
BibTex |
MLA
Цитировать
ГОСТ
Скопировать
Bouillon J. et al. Theoretical Study of Intramolecular Aldol Condensation of 1,6-Diketones: Trimethylsilyl Substituent Effect // Journal of Organic Chemistry. 2000. Vol. 65. No. 18. pp. 5823-5830.
ГОСТ со всеми авторами (до 50)
Скопировать
Bouillon J., Portella C., Bouquant J., Humbel S. Theoretical Study of Intramolecular Aldol Condensation of 1,6-Diketones: Trimethylsilyl Substituent Effect // Journal of Organic Chemistry. 2000. Vol. 65. No. 18. pp. 5823-5830.
Цитировать
RIS
Скопировать
TY - JOUR
DO - 10.1021/jo005544y
UR - https://pubs.acs.org/doi/10.1021/jo005544y
TI - Theoretical Study of Intramolecular Aldol Condensation of 1,6-Diketones: Trimethylsilyl Substituent Effect
T2 - Journal of Organic Chemistry
AU - Bouillon, Jean-Philippe
AU - Portella, Charles
AU - Bouquant, James
AU - Humbel, Stéphane
PY - 2000
DA - 2000/08/11
PB - American Chemical Society (ACS)
SP - 5823-5830
IS - 18
VL - 65
PMID - 10970329
SN - 0022-3263
SN - 1520-6904
ER -
Цитировать
BibTex (до 50 авторов)
Скопировать
@article{2000_Bouillon,
author = {Jean-Philippe Bouillon and Charles Portella and James Bouquant and Stéphane Humbel},
title = {Theoretical Study of Intramolecular Aldol Condensation of 1,6-Diketones: Trimethylsilyl Substituent Effect},
journal = {Journal of Organic Chemistry},
year = {2000},
volume = {65},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://pubs.acs.org/doi/10.1021/jo005544y},
number = {18},
pages = {5823--5830},
doi = {10.1021/jo005544y}
}
Цитировать
MLA
Скопировать
Bouillon, Jean-Philippe, et al. “Theoretical Study of Intramolecular Aldol Condensation of 1,6-Diketones: Trimethylsilyl Substituent Effect.” Journal of Organic Chemistry, vol. 65, no. 18, Aug. 2000, pp. 5823-5830. https://pubs.acs.org/doi/10.1021/jo005544y.