A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (−)-Hinesol
Тип публикации: Journal Article
Дата публикации: 2003-07-17
SCImago Q2
WOS Q1
БС1
SJR: 0.604
CiteScore: 5.8
Impact factor: 3.3
ISSN: 00223263, 15206904
PubMed ID:
12895091
Organic Chemistry
Краткое описание
In one step, the skeleton of cis-spirovetivanes was constructed with high stereoselectivity by the phosphine-catalyzed [3+2] cycloaddition reaction of tert-butyl 2,3-butadienoate or 2-butynoate with 3-methyl-2-methylenecyclohexanone (5). This method was exemplified by the first highly efficient total synthesis of natural product (-)-hinesol, which is an active ingredient of cerebral circulation and metabolism improvers.
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178
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ГОСТ
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Du Y., LU X. A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (−)-Hinesol // Journal of Organic Chemistry. 2003. Vol. 68. No. 16. pp. 6463-6465.
ГОСТ со всеми авторами (до 50)
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Du Y., LU X. A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (−)-Hinesol // Journal of Organic Chemistry. 2003. Vol. 68. No. 16. pp. 6463-6465.
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TY - JOUR
DO - 10.1021/jo034281f
UR - https://doi.org/10.1021/jo034281f
TI - A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (−)-Hinesol
T2 - Journal of Organic Chemistry
AU - Du, Yishu
AU - LU, XIYAN
PY - 2003
DA - 2003/07/17
PB - American Chemical Society (ACS)
SP - 6463-6465
IS - 16
VL - 68
PMID - 12895091
SN - 0022-3263
SN - 1520-6904
ER -
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BibTex (до 50 авторов)
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@article{2003_Du,
author = {Yishu Du and XIYAN LU},
title = {A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (−)-Hinesol},
journal = {Journal of Organic Chemistry},
year = {2003},
volume = {68},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jo034281f},
number = {16},
pages = {6463--6465},
doi = {10.1021/jo034281f}
}
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MLA
Скопировать
Du, Yishu, and XIYAN LU. “A Phosphine-Catalyzed [3+2] Cycloaddition Strategy Leading to the First Total Synthesis of (−)-Hinesol.” Journal of Organic Chemistry, vol. 68, no. 16, Jul. 2003, pp. 6463-6465. https://doi.org/10.1021/jo034281f.
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