Guerbet Reaction of Primary Alcohols Leading to β-Alkylated Dimer Alcohols Catalyzed by Iridium Complexes
Publication type: Journal Article
Publication date: 2006-09-21
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
17025333
Organic Chemistry
Abstract
[IrCl(cod)]2 and [Cp*IrCl2]2 complexes catalyzed efficiently the Guerbet reaction of primary alcohols to beta-alkylated dimer alcohols in good yields. For instance, the reaction of 1-butanol in the presence of [Cp*IrCl2]2 (1 mol %), t-BuOK (40 mol %), and 1,7-octadiene (10 mol %) produced 2-ethyl-1-hexanol in 93% yield. Various primary alcohols undergo the Guerbet reaction under the influence of Ir complexes to give the corresponding dimer alcohols in good yields. This method provides an alternative direct route to beta-alkylated primary alcohols which are prepared by aldol condensation of aldehydes followed by hydrogenation.
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136
Total citations:
136
Citations from 2024:
5
(3%)
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GOST
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Matsu-ura T. et al. Guerbet Reaction of Primary Alcohols Leading to β-Alkylated Dimer Alcohols Catalyzed by Iridium Complexes // Journal of Organic Chemistry. 2006. Vol. 71. No. 21. pp. 8306-8308.
GOST all authors (up to 50)
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Matsu-ura T., Sakaguchi S., Obora Y., Ishii Y. Guerbet Reaction of Primary Alcohols Leading to β-Alkylated Dimer Alcohols Catalyzed by Iridium Complexes // Journal of Organic Chemistry. 2006. Vol. 71. No. 21. pp. 8306-8308.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jo061400t
UR - https://doi.org/10.1021/jo061400t
TI - Guerbet Reaction of Primary Alcohols Leading to β-Alkylated Dimer Alcohols Catalyzed by Iridium Complexes
T2 - Journal of Organic Chemistry
AU - Matsu-ura, Toyomi
AU - Sakaguchi, Satoshi
AU - Obora, Yasushi
AU - Ishii, Yasutaka
PY - 2006
DA - 2006/09/21
PB - American Chemical Society (ACS)
SP - 8306-8308
IS - 21
VL - 71
PMID - 17025333
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2006_Matsu-ura,
author = {Toyomi Matsu-ura and Satoshi Sakaguchi and Yasushi Obora and Yasutaka Ishii},
title = {Guerbet Reaction of Primary Alcohols Leading to β-Alkylated Dimer Alcohols Catalyzed by Iridium Complexes},
journal = {Journal of Organic Chemistry},
year = {2006},
volume = {71},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/jo061400t},
number = {21},
pages = {8306--8308},
doi = {10.1021/jo061400t}
}
Cite this
MLA
Copy
Matsu-ura, Toyomi, et al. “Guerbet Reaction of Primary Alcohols Leading to β-Alkylated Dimer Alcohols Catalyzed by Iridium Complexes.” Journal of Organic Chemistry, vol. 71, no. 21, Sep. 2006, pp. 8306-8308. https://doi.org/10.1021/jo061400t.