volume 72 issue 20 pages 7504-7510

GaCl3-Catalyzed Insertion of Diazene Derivatives into the Cyclopropane Ring1

Publication typeJournal Article
Publication date2007-09-01
scimago Q2
wos Q1
SJR0.737
CiteScore6.1
Impact factor3.6
ISSN00223263, 15206904
PubMed ID:  17824644
Organic Chemistry
Abstract
GaCl3 has been found to efficiently catalyze the formal cycloadditions of diazene derivatives 6 onto 2-arylcyclopropane-1,1-dicarboxylates 5, giving rise to the pyrazolidine derivatives 7. The insertion into the cyclopropane ring proceeds with complete regioselectivity to furnish 5-arylpyrazolidine-1,2,3,3-tetracarboxylates exclusively; however, the cis-configured azo compound N-phenyltriazolinedione gave the two possible regioisomeric pyrazolidine derivatives in ratios varying from 1:1.5 to 1:3. Conceivable mechanisms of these transformations are being discussed.
Found 
Found 

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GOST |
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GOST Copy
Korotkov V. S. et al. GaCl3-Catalyzed Insertion of Diazene Derivatives into the Cyclopropane Ring1 // Journal of Organic Chemistry. 2007. Vol. 72. No. 20. pp. 7504-7510.
GOST all authors (up to 50) Copy
Korotkov V. S., Larionov O. V., Hofmeister A., Magull J., Meijere A. D. GaCl3-Catalyzed Insertion of Diazene Derivatives into the Cyclopropane Ring1 // Journal of Organic Chemistry. 2007. Vol. 72. No. 20. pp. 7504-7510.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/jo0704816
UR - https://doi.org/10.1021/jo0704816
TI - GaCl3-Catalyzed Insertion of Diazene Derivatives into the Cyclopropane Ring1
T2 - Journal of Organic Chemistry
AU - Korotkov, Vadim S
AU - Larionov, Oleg V.
AU - Hofmeister, Anja
AU - Magull, Jörg
AU - Meijere, Armin de
PY - 2007
DA - 2007/09/01
PB - American Chemical Society (ACS)
SP - 7504-7510
IS - 20
VL - 72
PMID - 17824644
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2007_Korotkov,
author = {Vadim S Korotkov and Oleg V. Larionov and Anja Hofmeister and Jörg Magull and Armin de Meijere},
title = {GaCl3-Catalyzed Insertion of Diazene Derivatives into the Cyclopropane Ring1},
journal = {Journal of Organic Chemistry},
year = {2007},
volume = {72},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/jo0704816},
number = {20},
pages = {7504--7510},
doi = {10.1021/jo0704816}
}
MLA
Cite this
MLA Copy
Korotkov, Vadim S., et al. “GaCl3-Catalyzed Insertion of Diazene Derivatives into the Cyclopropane Ring1.” Journal of Organic Chemistry, vol. 72, no. 20, Sep. 2007, pp. 7504-7510. https://doi.org/10.1021/jo0704816.