Synthesis, Structure, and Optical Properties of 1,4-Dithiafulvene-Based Nonlinear Optic-phores
Тип публикации: Journal Article
Дата публикации: 2007-07-24
SCImago Q2
WOS Q1
БС1
SJR: 0.604
CiteScore: 5.8
Impact factor: 3.3
ISSN: 00223263, 15206904
PubMed ID:
17645355
Organic Chemistry
Краткое описание
Polyenic nonlinear optic (NLO)-phores with a proaromatic 1,4-dithiafulvene electron donor and the little explored 1,1,3-tricyano-2-phenylpropene acceptor have been synthesized. Their configurational and conformational features, ground state polarization, and linear and nonlinear optical properties have been determined experimentally and theoretically, and the results are compared to those of tetrathiafulvalene-related derivatives. The newly prepared compounds show close to optimal bond length alternation values for maximizing the first molecular hyperpolarizability, and one of them displays the highest mu beta0 value ever reported for a dithiafulvene-based NLO-phore. The first example of a dithiafulvenylmethylene transfer reaction is also reported.
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Alías S. et al. Synthesis, Structure, and Optical Properties of 1,4-Dithiafulvene-Based Nonlinear Optic-phores // Journal of Organic Chemistry. 2007. Vol. 72. No. 17. pp. 6440-6446.
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Alías S., Andreu R., Blesa M. J., Mazuelas Franco S., Garín J., Gragera A., Orduna J., Romero P., Villacampa B., Allain M. Synthesis, Structure, and Optical Properties of 1,4-Dithiafulvene-Based Nonlinear Optic-phores // Journal of Organic Chemistry. 2007. Vol. 72. No. 17. pp. 6440-6446.
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TY - JOUR
DO - 10.1021/jo070694v
UR - https://doi.org/10.1021/jo070694v
TI - Synthesis, Structure, and Optical Properties of 1,4-Dithiafulvene-Based Nonlinear Optic-phores
T2 - Journal of Organic Chemistry
AU - Alías, Silvia
AU - Andreu, Raquel
AU - Blesa, María J
AU - Mazuelas Franco, Santiago
AU - Garín, Javier
AU - Gragera, Aurora
AU - Orduna, Jesús
AU - Romero, Pilar
AU - Villacampa, B.
AU - Allain, Magali
PY - 2007
DA - 2007/07/24
PB - American Chemical Society (ACS)
SP - 6440-6446
IS - 17
VL - 72
PMID - 17645355
SN - 0022-3263
SN - 1520-6904
ER -
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@article{2007_Alías,
author = {Silvia Alías and Raquel Andreu and María J Blesa and Santiago Mazuelas Franco and Javier Garín and Aurora Gragera and Jesús Orduna and Pilar Romero and B. Villacampa and Magali Allain},
title = {Synthesis, Structure, and Optical Properties of 1,4-Dithiafulvene-Based Nonlinear Optic-phores},
journal = {Journal of Organic Chemistry},
year = {2007},
volume = {72},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jo070694v},
number = {17},
pages = {6440--6446},
doi = {10.1021/jo070694v}
}
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MLA
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Alías, Silvia, et al. “Synthesis, Structure, and Optical Properties of 1,4-Dithiafulvene-Based Nonlinear Optic-phores.” Journal of Organic Chemistry, vol. 72, no. 17, Jul. 2007, pp. 6440-6446. https://doi.org/10.1021/jo070694v.
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