volume 77 issue 11 pages 4907-4916

Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes

Saori Naoe 1
Yamato Suzuki 1
Kimio Hirano 1
Yusuke Inaba 1
Taiji Asami 1
N. Fujii 1
Publication typeJournal Article
Publication date2012-05-15
scimago Q2
wos Q1
SJR0.737
CiteScore6.1
Impact factor3.6
ISSN00223263, 15206904
PubMed ID:  22568806
Organic Chemistry
Abstract
The gold-catalyzed cascade intermolecular addition-intramolecular carbocyclization reaction of dialkynylbenzenes was developed. In this reaction, regioselective addition of an external nucleophile toward the terminal alkyne and subsequent 6-endo-dig cyclization proceeded to give the 1,3-disubstituted naphthalenes in good yields. The direct synthesis of disubstituted chrysenes via a gold-catalyzed addition and double cyclization cascade using a triyne-type substrate was also achieved.
Found 
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GOST Copy
Naoe S. et al. Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes // Journal of Organic Chemistry. 2012. Vol. 77. No. 11. pp. 4907-4916.
GOST all authors (up to 50) Copy
Naoe S., Suzuki Y., Hirano K., Inaba Y., Asami T., Fujii N., Ohno H. Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes // Journal of Organic Chemistry. 2012. Vol. 77. No. 11. pp. 4907-4916.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/jo300771f
UR - https://doi.org/10.1021/jo300771f
TI - Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes
T2 - Journal of Organic Chemistry
AU - Naoe, Saori
AU - Suzuki, Yamato
AU - Hirano, Kimio
AU - Inaba, Yusuke
AU - Asami, Taiji
AU - Fujii, N.
AU - Ohno, Hiroaki
PY - 2012
DA - 2012/05/15
PB - American Chemical Society (ACS)
SP - 4907-4916
IS - 11
VL - 77
PMID - 22568806
SN - 0022-3263
SN - 1520-6904
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2012_Naoe,
author = {Saori Naoe and Yamato Suzuki and Kimio Hirano and Yusuke Inaba and Taiji Asami and N. Fujii and Hiroaki Ohno},
title = {Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes},
journal = {Journal of Organic Chemistry},
year = {2012},
volume = {77},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/jo300771f},
number = {11},
pages = {4907--4916},
doi = {10.1021/jo300771f}
}
MLA
Cite this
MLA Copy
Naoe, Saori, et al. “Gold(I)-Catalyzed Regioselective Inter-/Intramolecular Addition Cascade of Di- and Triynes for Direct Construction of Substituted Naphthalenes.” Journal of Organic Chemistry, vol. 77, no. 11, May. 2012, pp. 4907-4916. https://doi.org/10.1021/jo300771f.