Journal of Organic Chemistry

, volume 78 , issue 16 , pages 7777-7784

"Two functional groups in one package": using both alkyne π-bonds in cascade transformations.

Igor V. Alabugin ¹

Brian Gold ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306-4390, United States |

Publication type: Journal Article

Publication date: 2013-07-17

American Chemical Society (ACS)

Journal of Organic Chemistry

scimago Q2

wos Q1

SJR: 0.737

CiteScore: 6.1

Impact factor: 3.6

ISSN: 00223263, 15206904

DOI: 10.1021/jo401091w

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PubMed ID: 23829276

Organic Chemistry

Abstract

Spatial orthogonality of the two independently addressable π-systems in alkynes can be used for the design and control of metal-free cascade transformations. Examples include ionic chemistry of neutral hydrocarbons, preparation of radicals without radical initiators, generation of excited states without light, "1,2-dicarbene reactivity" of alkynes in "boomerang" radical processes, selective conversion of alkynes into carbonyl compounds, and full disassembly of the alkyne moiety.

Found

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Alabugin I. V., Gold B. "Two functional groups in one package": using both alkyne π-bonds in cascade transformations. // Journal of Organic Chemistry. 2013. Vol. 78. No. 16. pp. 7777-7784.

GOST all authors (up to 50) Copy

Alabugin I. V., Gold B. "Two functional groups in one package": using both alkyne π-bonds in cascade transformations. // Journal of Organic Chemistry. 2013. Vol. 78. No. 16. pp. 7777-7784.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/jo401091w

UR - https://doi.org/10.1021/jo401091w

TI - "Two functional groups in one package": using both alkyne π-bonds in cascade transformations.

T2 - Journal of Organic Chemistry

AU - Alabugin, Igor V.

AU - Gold, Brian

PY - 2013

DA - 2013/07/17

PB - American Chemical Society (ACS)

SP - 7777-7784

IS - 16

VL - 78

PMID - 23829276

SN - 0022-3263

SN - 1520-6904

ER -

BibTex |

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BibTex (up to 50 authors) Copy

@article{2013_Alabugin,

author = {Igor V. Alabugin and Brian Gold},

title = {"Two functional groups in one package": using both alkyne π-bonds in cascade transformations.},

journal = {Journal of Organic Chemistry},

year = {2013},

volume = {78},

publisher = {American Chemical Society (ACS)},

month = {jul},

url = {https://doi.org/10.1021/jo401091w},

number = {16},

pages = {7777--7784},

doi = {10.1021/jo401091w}

}

MLA

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MLA Copy

Alabugin, Igor V., and Brian Gold. “"Two functional groups in one package": using both alkyne π-bonds in cascade transformations..” Journal of Organic Chemistry, vol. 78, no. 16, Jul. 2013, pp. 7777-7784. https://doi.org/10.1021/jo401091w.