Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides
Publication type: Journal Article
Publication date: 2009-09-15
scimago Q2
wos Q1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
PubMed ID:
19754108
Organic Chemistry
Abstract
Rhodium-catalyzed carbozincation of ynamides using diorganozinc reagents or functionalized organozinc halides is described. Using a tri(2-furyl)phosphine-modified rhodium catalyst, the reaction course is altered to hydrozincation when diethylzinc is employed as the organozinc reagent. Trapping of the alkenylzinc intermediates produced in these reactions in further functionalization reactions is possible. Collectively, these processes enable access to a range of multisubstituted enamides in stereo- and regiocontrolled fashion.
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86
Total citations:
86
Citations from 2024:
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(5%)
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MLA
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GOST
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Gourdet B. et al. Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides // Journal of Organic Chemistry. 2009. Vol. 74. No. 20. pp. 7849-7858.
GOST all authors (up to 50)
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Gourdet B., Rudkin M. E., Watts C. A., Lam H. W. Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides // Journal of Organic Chemistry. 2009. Vol. 74. No. 20. pp. 7849-7858.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/jo901658v
UR - https://doi.org/10.1021/jo901658v
TI - Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides
T2 - Journal of Organic Chemistry
AU - Gourdet, Benoit
AU - Rudkin, Mairi E
AU - Watts, Ciorsdaidh A
AU - Lam, Hon Wai
PY - 2009
DA - 2009/09/15
PB - American Chemical Society (ACS)
SP - 7849-7858
IS - 20
VL - 74
PMID - 19754108
SN - 0022-3263
SN - 1520-6904
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2009_Gourdet,
author = {Benoit Gourdet and Mairi E Rudkin and Ciorsdaidh A Watts and Hon Wai Lam},
title = {Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides},
journal = {Journal of Organic Chemistry},
year = {2009},
volume = {74},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/jo901658v},
number = {20},
pages = {7849--7858},
doi = {10.1021/jo901658v}
}
Cite this
MLA
Copy
Gourdet, Benoit, et al. “Preparation of Multisubstituted Enamides via Rhodium-Catalyzed Carbozincation and Hydrozincation of Ynamides.” Journal of Organic Chemistry, vol. 74, no. 20, Sep. 2009, pp. 7849-7858. https://doi.org/10.1021/jo901658v.