Effect of Substituents on the Structure of the Vinyl Radical:  Calculations and Experiments

Literature reports indicate either a linear or a bent configuration for α-substituted vinyl radicals. In order to get a better insight into this structural question, calculations of the structure of some α-substituted vinyl radicals were conducted by the DFT approach [BLYP/6-31G(d,p) and B3LYP/6-311G(2d,2p)]. For vinyl radicals bearing σ-type substituents (Me, SH, Cl, OH, F), the bent form is found to be the minimum energy structure; the inversion barrier of the E and Z forms is found to markedly increase as the electronegativity of the group increases. Vinyl radicals bearing π-type substituents (CHCH2, CHO, CN, C6H5) are found to be linear. The effect of β-substituents is much lower, and the β-fluoro- and β-ethenylvinyl radicals, representative of σ- and π-type substituents, are calculated to be bent. Comparison with other literature calculations, obtained by different methods for some similar vinylic radicals, supports our computational results. Experimental support was also sought, with particular rega...