A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds
Тип публикации: Journal Article
Дата публикации: 1997-10-01
scimago Q2
wos Q1
БС1
SJR: 0.737
CiteScore: 6.1
Impact factor: 3.6
ISSN: 00223263, 15206904
Organic Chemistry
Краткое описание
Catalytic amounts of 2,2,6,6-tetramethyl-1-piperidinyloxyl (TEMPO) are used in combination with [bis(acetoxy)iodo]benzene (BAIB) as a stoichiometric oxidant in the conversion of primary and secondary alcohols to carbonyl compounds. This procedure works efficiently at room temperature in almost all common solvents and neat in some cases. This process exhibits a very high degree of selectivity for the oxidation of primary alcohols to aldehydes, without any noticeable overoxidation to carboxyl compounds, and a high chemoselectivity in the presence of either secondary alcohols or of other oxidizable moieties. This procedure allows an easy, convenient, high-yielding method for the oxidation of alcohols starting from commercially available compounds.
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ГОСТ
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De Mico A. et al. A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds // Journal of Organic Chemistry. 1997. Vol. 62. No. 20. pp. 6974-6977.
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De Mico A., Margarita R., Parlanti L., Vescovi A., Piancatelli G. A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds // Journal of Organic Chemistry. 1997. Vol. 62. No. 20. pp. 6974-6977.
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TY - JOUR
DO - 10.1021/jo971046m
UR - https://doi.org/10.1021/jo971046m
TI - A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds
T2 - Journal of Organic Chemistry
AU - De Mico, Antonella
AU - Margarita, Roberto
AU - Parlanti, Luca
AU - Vescovi, Andrea
AU - Piancatelli, Giovanni
PY - 1997
DA - 1997/10/01
PB - American Chemical Society (ACS)
SP - 6974-6977
IS - 20
VL - 62
SN - 0022-3263
SN - 1520-6904
ER -
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@article{1997_De Mico,
author = {Antonella De Mico and Roberto Margarita and Luca Parlanti and Andrea Vescovi and Giovanni Piancatelli},
title = {A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds},
journal = {Journal of Organic Chemistry},
year = {1997},
volume = {62},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/jo971046m},
number = {20},
pages = {6974--6977},
doi = {10.1021/jo971046m}
}
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MLA
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De Mico, Antonella, et al. “A Versatile and Highly Selective Hypervalent Iodine (III)/2,2,6,6-Tetramethyl-1-piperidinyloxyl-Mediated Oxidation of Alcohols to Carbonyl Compounds.” Journal of Organic Chemistry, vol. 62, no. 20, Oct. 1997, pp. 6974-6977. https://doi.org/10.1021/jo971046m.