A Small-Angle Neutron and Static Light Scattering Study of Micelles Formed in Aqueous Mixtures of a Nonionic Alkylglucoside and an Anionic Surfactant
Тип публикации: Journal Article
Дата публикации: 2005-06-01
scimago Q1
wos Q3
БС2
SJR: 0.742
CiteScore: 5.3
Impact factor: 2.9
ISSN: 15206106, 15205207, 10895647
PubMed ID:
16852532
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Краткое описание
The size and shape of micelles formed in aqueous mixtures of the anionic surfactant sodium dodecyl sulfate (SDS) and the nonionic sugar-based surfactant n-decyl beta-D-glucopyranoside (C(10)G) at different concentrations of added salt have been investigated with small-angle neutron and static light scattering. Rather small prolate ellipsoidal micelles form in the absence of added salt and at [NaCl] = 10 mM in D(2)O. The micelles grow considerably in length to large rods as the electrolyte concentration is raised to [NaCl] = 0.1 M. In excess of nonionic surfactant ([SDS]/[C(10)G] = 1:3) at [NaCl] = 0.1 M in D(2)O, several thousands of Angstroms long wormlike micelles are observed. Most interestingly, a conspicuously large isotope solvent effect was observed from static light scattering data according to which micelles formed at [SDS]/[C(10)G] = 1:3 and [NaCl] = 0.1 M in H(2)O are at least five times smaller than micelles formed in the corresponding samples in D(2)O.
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Bergström L. M., Bastardo L. A., Garamus V. M. A Small-Angle Neutron and Static Light Scattering Study of Micelles Formed in Aqueous Mixtures of a Nonionic Alkylglucoside and an Anionic Surfactant // Journal of Physical Chemistry B. 2005. Vol. 109. No. 25. pp. 12387-12393.
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Bergström L. M., Bastardo L. A., Garamus V. M. A Small-Angle Neutron and Static Light Scattering Study of Micelles Formed in Aqueous Mixtures of a Nonionic Alkylglucoside and an Anionic Surfactant // Journal of Physical Chemistry B. 2005. Vol. 109. No. 25. pp. 12387-12393.
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TY - JOUR
DO - 10.1021/jp051113d
UR - https://doi.org/10.1021/jp051113d
TI - A Small-Angle Neutron and Static Light Scattering Study of Micelles Formed in Aqueous Mixtures of a Nonionic Alkylglucoside and an Anionic Surfactant
T2 - Journal of Physical Chemistry B
AU - Bergström, L M
AU - Bastardo, Luis A
AU - Garamus, Vasil M.
PY - 2005
DA - 2005/06/01
PB - American Chemical Society (ACS)
SP - 12387-12393
IS - 25
VL - 109
PMID - 16852532
SN - 1520-6106
SN - 1520-5207
SN - 1089-5647
ER -
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@article{2005_Bergström,
author = {L M Bergström and Luis A Bastardo and Vasil M. Garamus},
title = {A Small-Angle Neutron and Static Light Scattering Study of Micelles Formed in Aqueous Mixtures of a Nonionic Alkylglucoside and an Anionic Surfactant},
journal = {Journal of Physical Chemistry B},
year = {2005},
volume = {109},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/jp051113d},
number = {25},
pages = {12387--12393},
doi = {10.1021/jp051113d}
}
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MLA
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Bergström, L. M., et al. “A Small-Angle Neutron and Static Light Scattering Study of Micelles Formed in Aqueous Mixtures of a Nonionic Alkylglucoside and an Anionic Surfactant.” Journal of Physical Chemistry B, vol. 109, no. 25, Jun. 2005, pp. 12387-12393. https://doi.org/10.1021/jp051113d.