Journal of Physical Chemistry B, volume 110, issue 2, pages 671-673

Multigram Scale, Solventless, and Diffusion-Controlled Route to Highly Monodisperse PbS Nanocrystals

Publication typeJournal Article
Publication date2005-12-22
Quartile SCImago
Q1
Quartile WOS
Q3
Impact factor3.3
ISSN15206106, 15205207
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Abstract
High-quality PbS nanocrystals were produced in multigram-scale quantities through a solventless, heterogeneous, and relatively green route. The heterogeneous nature of this reaction allows one to limit the diffusion in the system, allowing for unprecedented monodispersity and quality of the product demonstrated by a full-width at half-maximum of the photoluminescence peak (PL fwhm) as low as 52 meV, a Stokes shift as low as 10 meV, and a quantum yield (QY) of 40%. The growth of the nanocrystals is interpreted in the framework of a diffusion-controlled Ostwald growth in conditions of strong supersaturation.

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GOST |
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GOST Copy
Cademartiri L. et al. Multigram Scale, Solventless, and Diffusion-Controlled Route to Highly Monodisperse PbS Nanocrystals // Journal of Physical Chemistry B. 2005. Vol. 110. No. 2. pp. 671-673.
GOST all authors (up to 50) Copy
Cademartiri L., Bertolotti J., Sapienza R., Wiersma D. S., von Freymann G., Ozin G. A. Multigram Scale, Solventless, and Diffusion-Controlled Route to Highly Monodisperse PbS Nanocrystals // Journal of Physical Chemistry B. 2005. Vol. 110. No. 2. pp. 671-673.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/jp0563585
UR - https://doi.org/10.1021/jp0563585
TI - Multigram Scale, Solventless, and Diffusion-Controlled Route to Highly Monodisperse PbS Nanocrystals
T2 - Journal of Physical Chemistry B
AU - Cademartiri, Ludovico
AU - Bertolotti, Jacopo
AU - Sapienza, Riccardo
AU - Wiersma, Diederik S.
AU - von Freymann, Georg
AU - Ozin, G A.
PY - 2005
DA - 2005/12/22 00:00:00
PB - American Chemical Society (ACS)
SP - 671-673
IS - 2
VL - 110
SN - 1520-6106
SN - 1520-5207
ER -
BibTex |
Cite this
BibTex Copy
@article{2005_Cademartiri,
author = {Ludovico Cademartiri and Jacopo Bertolotti and Riccardo Sapienza and Diederik S. Wiersma and Georg von Freymann and G A. Ozin},
title = {Multigram Scale, Solventless, and Diffusion-Controlled Route to Highly Monodisperse PbS Nanocrystals},
journal = {Journal of Physical Chemistry B},
year = {2005},
volume = {110},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/jp0563585},
number = {2},
pages = {671--673},
doi = {10.1021/jp0563585}
}
MLA
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MLA Copy
Cademartiri, Ludovico, et al. “Multigram Scale, Solventless, and Diffusion-Controlled Route to Highly Monodisperse PbS Nanocrystals.” Journal of Physical Chemistry B, vol. 110, no. 2, Dec. 2005, pp. 671-673. https://doi.org/10.1021/jp0563585.
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