Order parameters 〈p2 〉, 〈p4 〉, and 〈p6 〉 of aligned nematic liquid-crystalline polymer as determined by numerical simulation of electron paramagnetic resonance spectra
Publication type: Journal Article
Publication date: 2012-05-14
scimago Q1
wos Q3
SJR: 0.742
CiteScore: 5.3
Impact factor: 2.9
ISSN: 15206106, 15205207, 10895647
PubMed ID:
22537209
Materials Chemistry
Surfaces, Coatings and Films
Physical and Theoretical Chemistry
Abstract
High rank order parameters may comprise substantial information about molecular orientational distribution of liquid-crystalline materials. There are few experimental procedures targeted at the determination of high rank order parameters. We suggest a procedure for the determination of order parameters of a spin probe by numerical simulation of electron paramagnetic resonance (EPR) spectra. The procedure is based on revealing the molecular orientation axis of a spin probe. Order parameters , , and of the spin probe in aligned liquid-crystalline polymer have been measured by the suggested procedure. It was shown that the procedure gives more reliable and complete characteristics of molecular order than does polarized UV-visible spectroscopy.
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32
Total citations:
32
Citations from 2024:
6
(18.75%)
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Yankova T. et al. Order parameters 〈p2〉, 〈p4〉, and 〈p6〉 of aligned nematic liquid-crystalline polymer as determined by numerical simulation of electron paramagnetic resonance spectra // Journal of Physical Chemistry B. 2012. Vol. 116. No. 20. pp. 6010-6016.
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Yankova T., Yankova T. S., Bobrovsky A., Vorobiev A. K., Vorobiev A. Kh. Order parameters 〈p2〉, 〈p4〉, and 〈p6〉 of aligned nematic liquid-crystalline polymer as determined by numerical simulation of electron paramagnetic resonance spectra // Journal of Physical Chemistry B. 2012. Vol. 116. No. 20. pp. 6010-6016.
Cite this
RIS
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TY - JOUR
DO - 10.1021/jp301170b
UR - https://pubs.acs.org/doi/10.1021/jp301170b
TI - Order parameters 〈p2〉, 〈p4〉, and 〈p6〉 of aligned nematic liquid-crystalline polymer as determined by numerical simulation of electron paramagnetic resonance spectra
T2 - Journal of Physical Chemistry B
AU - Yankova, T.
AU - Yankova, T S
AU - Bobrovsky, A.Yu
AU - Vorobiev, Andrey Kh.
AU - Vorobiev, A Kh
PY - 2012
DA - 2012/05/14
PB - American Chemical Society (ACS)
SP - 6010-6016
IS - 20
VL - 116
PMID - 22537209
SN - 1520-6106
SN - 1520-5207
SN - 1089-5647
ER -
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BibTex (up to 50 authors)
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@article{2012_Yankova,
author = {T. Yankova and T S Yankova and A.Yu Bobrovsky and Andrey Kh. Vorobiev and A Kh Vorobiev},
title = {Order parameters 〈p2〉, 〈p4〉, and 〈p6〉 of aligned nematic liquid-crystalline polymer as determined by numerical simulation of electron paramagnetic resonance spectra},
journal = {Journal of Physical Chemistry B},
year = {2012},
volume = {116},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://pubs.acs.org/doi/10.1021/jp301170b},
number = {20},
pages = {6010--6016},
doi = {10.1021/jp301170b}
}
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MLA
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Yankova, T., et al. “Order parameters 〈p2〉, 〈p4〉, and 〈p6〉 of aligned nematic liquid-crystalline polymer as determined by numerical simulation of electron paramagnetic resonance spectra.” Journal of Physical Chemistry B, vol. 116, no. 20, May. 2012, pp. 6010-6016. https://pubs.acs.org/doi/10.1021/jp301170b.
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